31661-15-1

Basic information

• Product Name: dibenzyl aminomalonate
• Synonyms: dibenzyl aminomalonate
• CAS NO: 31661-15-1
• Molecular Weight: 299.326
• Mol File: 31661-15-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: dibenzyl aminomalonate(CAS DataBase Reference)
• NIST Chemistry Reference: dibenzyl aminomalonate(31661-15-1)
• EPA Substance Registry System: dibenzyl aminomalonate(31661-15-1)

Safety Data

• Hazardous Substances Data: 31661-15-1(Hazardous Substances Data)

Upstream product

• 51118-40-2 dibenzyl 2-(hydroxyimino)malonate 
• 15014-25-2 malonic acid dibenzyl ester 

Downstream Products

• 865879-17-0 benzyl N-[N-t-butoxycarbonylsarcosyl]-2-benzyloxycarbonylglycinate 
• 855652-93-6 benzyloxycarbonylamino-(2-phenyl-indol-3-ylmethyl)-malonic acid dibenzyl ester 
• 78033-34-8 benzyl (2-oxo-3-phenylacetamido-4-styryl-1-azetidinyl)malonate 
• 78033-36-0 (5R,6R)-7-Oxo-6-phenylacetylamino-3-oxa-1-aza-bicyclo[3.2.0]heptane-2,2-dicarboxylic acid dibenzyl ester 
• 78033-35-9 benzyl (4-hydroxymethyl-2-oxo-3-phenylacetamido-1-azetidinyl)malonate 
• 64789-45-3 benzyl N-<(RS)-α-(methoxycarbonyl)-β-phenylpropionyl>-N'-(benzyloxycarbonyl)-α,α-diaminoacetate 
• 72594-96-8 N-(benzyloxycarbonyl)-(RS)-2-aminomalonic acid (tert-butyloxycarbonyl)hydrazidyl benzyl ester 
• 66187-03-9 Azidocarbonyl-benzyloxycarbonylamino-acetic acid benzyl ester 
• 66187-02-8 Benzyloxycarbonylamino-isocyanato-acetic acid benzyl ester 
• 40204-01-1 N-(benzyloxycarbonyl)-(RS)-2-aminomalonic acid benzyl ester 
• 64789-44-2 Amino-benzyloxycarbonylamino-acetic acid benzyl ester 
• 66293-41-2 benzyl N-(benzyloxycarbonyl)-N'-(tert-butyloxycarbonyl)-α,α-diaminoacetate 

Relevant articles and documents

The synthetic versatility of alkoxycarbonyl- and hydroxymethyl-piperazine- 2,5-diones

Alkoxycarbonylpiperazine-2,5-diones are versatile precursors for the α-functionalisation of piperazine-2,5-diones. The alkoxycarbonyl group activates the α-carbon position to alkylation reactions and this provides a mild and selective method for the extension of the carbon framework of piperazine-2,5-diones. In addition, the alkoxycarbonyl group can be converted to the carboxy group, which in turn can be 'deleted' or manipulated for the installation of carbon and/or heteroatom substituents where desired, the latter via N-acyliminium chemistry. We also demonstrate that hydroxymethylpiperazine-2, 5-diones complement carboxypiperazinediones as precursors for the generation of N-acyliminium ions.