31885-97-9Relevant articles and documents
METHOD FOR PREPARING DOUBLE-SEALED-END GLYCOL ETHER
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Paragraph 0030; 0037, (2017/12/27)
Disclosed is a method for preparing a double end capped glycol ether, the method comprising: introducing into a reactor a raw material comprising a glycol monoether and a monohydric alcohol ether, and enabling the raw material to contact and react with an acidic molecular sieve catalyst to generate a double end capped glycol ether, a reaction temperature being 50-300° C., a reaction pressure being 0.1-15 MPa, a WHSV of the glycol monoether in the raw material being 0.01-15.0 h?1, and a mole ratio of the monohydric alcohol ether to the glycol monoether in the raw material being 1-100:1. The method of the present invention enables a long single-pass lifespan of the catalyst and repeated regeneration, has a high yield and selectivity of a target product, low energy consumption during separation of the product, a high economic value of a by-product, and is flexible in production scale and application.
Special features of preparing benzoaza-12-crown-4 by condensation of o-aminophenol with triethylene glycol dichloride
Glushko,Blokhina,Sadovskaya, N. Yu,Pevtsova,Belus
, p. 2079 - 2083 (2015/02/19)
Preparative method of benzoaza-12-crown-4 preparation via condensation of o-aminophenol with trietylene glycol dichloride using sodium hydroxide as the template agent has been studied at elevated temperature in 2-propanol and n-butanol. Kinetics of the reaction mixture composition change in the course of the process has been investigated by GLC. Performing the reaction in 2-propanol leads to a higher yield of benzoaza-12-crown-4.
CATALYSTS FOR THE PRODUCTION OF HYDROXY ETHER HYDROCARBONS BY VAPOR PHASE HYDROGENOLYSIS OF CYCLIC ACETALS AND KETALS
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Page/Page column 18, (2013/02/28)
Catalyst compositions of palladium supported on alumina or zirconium oxide supports having low or no silicon dioxide contents and having a specific surface area or modified with alkali, alkaline earth, or phosphine oxide compounds are selective in a vapor phase hydrogenolysis reaction to convert cyclic acetal compounds and/or cyclic ketal compounds in the presence of hydrogen to their corresponding hydroxy ether hydrocarbon reaction products.