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111-76-2 Usage

Description

2-Butoxyethanol is a clear, colourless liquid with ether-like smell.2-Butoxyethanol is usually produced by a reaction of ethylene oxide with butyl alcohol, but it may also be made by the reaction of ethylene glycol with dibutyl sulphate. 2-Butoxyethanol is widely used as a solvent in protective surface coatings such as spray lacquers, quick-dry lacquers, enamels, varnishes, and latex paints. It is also used as an ingredient in paint thinners and strippers, varnish removers, agricultural chemicals, herbicides, silicon caulks, cutting oils, and hydraulic fluids and as metal cleaners, fabric dyes and inks, industrial and household cleaners (as a degreaser), and dry-cleaning compounds. It is also used in liquid soaps and in cosmetics. 2-Butoxyethanol acetate has been reported to be present in air, water, and soil as a contaminant and exposure to it occurs during its manufacture and use as an intermediate in the chemical industry, and during the formulation and use of its products in multiple industrial activities. The acetate form of 2-butoxyethanol is 2-butoxyethanol acetate and also known as ethylene glycol monobutyl ether acetate.

Chemical Properties

2-Butoxyethanol is a clear colorless liquid with an ether-like smell and belongs to the family of glycol ether/alkoxy alcohol. 2-Butoxyethanol is miscible in water and soluble in most organic solvents. 2-Butoxyethanol does not occur naturally. It is usually produced by reacting ethylene oxide with butyl alcohol. 2-Butoxyethanol is used as a solvent for nitrocellulose, natural and synthetic resins, soluble oils, in surface coatings, spray lacquers, enamels, varnishes, and latex paints, as an ingredient in paint thinners, quick-dry lacquers, latex paint, and strippers, varnish removers, and herbicides. It is also used in textile dyeing and printing, in the treatment of leather, in the production of plasticizers, as a stabilizer in metal cleaners and household cleaners, and in hydraulic fl uids, insecticides, herbicides, and rust removers. It is also used as an ingredient in liquid soaps, cosmetics, industrial and household cleaners, dry-cleaning compounds, and as an ingredient in silicon caulks, cutting oils, and hydraulic fluids. 2-Butoxyethanol is a fire hazard when exposed to heat, sparks, or open flames.

Physical properties

Clear, colorless, oily liquid with a mild, ether-like odor. Experimentally determined detection and recognition odor threshold concentrations were 500 μg/m3 (100 ppbv) and 1.7 mg/m3 (350 ppbv), respectively (Hellman and Small, 1974). An odor threshold concentration of 580 ppbv was reported by Nagata and Takeuchi (1990).

Uses

Different sources of media describe the Uses of 111-76-2 differently. You can refer to the following data:
1. 2-Butoxyethanol is a reagent in the synthesis of 4-butoxyethoxy-N-octadecyl-1,8-naphthalimide as a new fluorescent probe for the determination of proteins. Also used as a reagent in the synthesis of 4-hydroxybenzaldehyde derivatives as tyrosinase inhibitors.
2. Ethylene glycol n-butyl ether (EB) is used widely as a coupling solvent because of its superior coupling efficiency and excellent solvency for resins.
3. Ethylene glycol monobutyl ether (EGBE) is used as a solvent for nitrocellulose, resins, oil, and grease, and in dry cleaning.
4. Solvent for nitrocellulose, resins, grease, oil, albumin; dry cleaning.

Synthesis Reference(s)

The Journal of Organic Chemistry, 45, p. 1095, 1980 DOI: 10.1021/jo01294a034

General Description

A colorless liquid with a mild, pleasant odor. Less dense than water. Flash point 160°F. Irritates skin and eyes and may be toxic by ingestion. Used as a solvent and to make paints and varnish.

Air & Water Reactions

2-Butoxyethanol is sensitive to air and light. Slightly soluble in water.

Reactivity Profile

ETHYLENE GLYCOL N-BUTYL ETHER may react with bases, aluminum and oxidizing materials. 2-Butoxyethanol is liable to form peroxides on exposure to air and light. 2-Butoxyethanol attacks some forms of plastics, rubber and coatings. .

Hazard

A toxic material. Eye and upper respiratory tract irritant. Questionable carcinogen.

Health Hazard

2-Butoxyethanol is present in a variety of consumer products, including cleaning agents and surface coatings, such as paints, lacquers, and varnishes. 2-Butoxyethanol is readily absorbed following inhalation, oral, and dermal exposure. 2-Butoxyethanol is released into air or water by different industrial activities and facilities that manu facture, process, or use the chemical. Exposure to 2-butoxyethanol causes irritating effects to the eyes and skin, but it has not induced skin sensitization in guinea pigs. Information on the human health effects associated with exposure to 2-butoxyethanol is limited. However, case studies of individuals who had attempted suicide by ingest ing 2-butoxyethanol-containing cleaning solutions suffered poisoning with symp toms such as hemoglobinuria, erythropenia, and hypotension, metabolic acidosis, shock, non-cardiogenic pulmonary edema, and albuminuria, hepatic disorders and hematuria.

Fire Hazard

Combustible material: may burn but does not ignite readily. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.

Chemical Reactivity

Reactivity with Water No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

Safety Profile

Poison by ingestion, skin contact, intraperitoneal, and intravenous routes. Moderately toxic via inhalation and subcutaneous routes. Human systemic effects by inhalation: nausea or vomiting, headache, unspecified eye effects. Experimental teratogenic and reproductive effects. A skin irritant. Combustible liquid when exposed to heat or flame. To fight fire, use foam, CO2, dry chemical. Incompatible with oxidizing materials, heat, and flame. When heated to decomposition it emits acrid smoke and irritating fumes

Potential Exposure

2-Butoxy ethanol is a colorless liquid with a mild, ether like odor. Molecular weight 5 118.20; Specific gravity (H2O:1) 5 0.90; boiling point 5 171C; freezing/ melting point 5 274.8C; vapor pressure 5 0.8 mmHg @ 20C; Relative vapor density (air 5 1) 5 4.1; Flash point = 61C (cc); Autoignition temperature = 238C

Environmental fate

Biological. Bridié et al. (1979) reported BOD and COD values of 0.71 and 2.20 g/g using filtered effluent from a biological sanitary waste treatment plant. These values were determined using a standard dilution method at 20 °C for a period of 5 d. When a sewage seed was used in a separate screening test, a BOD value of 0.20 g/g was obtained. The ThOD for 2-butoxyethanol is 2.31 g/g. Chemical/Physical. At an influent concentration of 1,000 mg/L, treatment with GAC resulted in an effluent concentration of 441 mg/L. The adsorbability of the carbon used was 112 mg/g carbon (Guisti et al., 1974).

storage

2-Butoxyethanol should be kept stored in tightly closed, grounded containers in a cool area with adequate ventilation, away from normal work areas and sources of heat and sparks, and electrical equipment. At the storage and handling area, workers should use solvent resistant materials.

Purification Methods

Peroxides can be removed by refluxing with anhydrous SnCl2 or by passage under slight pressure through a column of activated alumina. Dry with anhydrous K2CO3 and CaSO4, filter and distil, or reflux with, and distil from NaOH. [Beilstein 1 IV 2380.]

Incompatibilities

May form explosive mixture with air. Can form unstable and explosive peroxides; check for peroxides prior to distillation; render harmless if positive. Decomposes, producing toxic fumes. Violent reaction with strong caustics and strong oxidizers. Attacks some coatings, plastics and rubber. Attacks metallic aluminum at high temperatures.

Waste Disposal

EGBE is destroyed by burning in an incinerator. In the laboratory, small amounts may be disposed of in the sink with a large volume of water.

Precautions

Occupational workers should use minimal quantities of 2-butoxyethanol in designated areas with adequate ventilation and away from sources of heat or sparks. Whenever pos sible, fi re-resistant containers should be used. Wear appropriate protective equipment to prevent skin and eye contact.

Check Digit Verification of cas no

The CAS Registry Mumber 111-76-2 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,1 and 1 respectively; the second part has 2 digits, 7 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 111-76:
(5*1)+(4*1)+(3*1)+(2*7)+(1*6)=32
32 % 10 = 2
So 111-76-2 is a valid CAS Registry Number.
InChI:InChI=1/C6H14O2/c1-3-4-5-8-6(2)7/h6-7H,3-5H2,1-2H3

111-76-2 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • TCI America

  • (B0698)  Ethylene Glycol Monobutyl Ether  >99.0%(GC)

  • 111-76-2

  • 25mL

  • 95.00CNY

  • Detail
  • TCI America

  • (B0698)  Ethylene Glycol Monobutyl Ether  >99.0%(GC)

  • 111-76-2

  • 500mL

  • 195.00CNY

  • Detail
  • Alfa Aesar

  • (A17976)  2-n-Butoxyethanol, 99%   

  • 111-76-2

  • 5ml

  • 57.0CNY

  • Detail
  • Alfa Aesar

  • (A17976)  2-n-Butoxyethanol, 99%   

  • 111-76-2

  • 100ml

  • 112.0CNY

  • Detail
  • Alfa Aesar

  • (A17976)  2-n-Butoxyethanol, 99%   

  • 111-76-2

  • 500ml

  • 219.0CNY

  • Detail
  • Alfa Aesar

  • (A17976)  2-n-Butoxyethanol, 99%   

  • 111-76-2

  • 2500ml

  • 610.0CNY

  • Detail
  • Alfa Aesar

  • (A17976)  2-n-Butoxyethanol, 99%   

  • 111-76-2

  • 10000ml

  • 1383.0CNY

  • Detail
  • Riedel-de Haën

  • (92328)  Ethyleneglycolbutylether  TraceSELECT®, for inorganic trace analysis, ≥99.5%

  • 111-76-2

  • 92328-1L

  • 1,021.41CNY

  • Detail
  • Sigma-Aldrich

  • (256366)  Ethyleneglycolbutylether  spectrophotometric grade, ≥99.0%

  • 111-76-2

  • 256366-1L

  • 1,258.92CNY

  • Detail
  • Sigma-Aldrich

  • (256366)  Ethyleneglycolbutylether  spectrophotometric grade, ≥99.0%

  • 111-76-2

  • 256366-2L

  • 1,884.87CNY

  • Detail
  • Sigma-Aldrich

  • (537551)  Ethyleneglycolbutylether  ≥99%

  • 111-76-2

  • 537551-1L-A

  • 535.86CNY

  • Detail

111-76-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-butoxyethanol

1.2 Other means of identification

Product number -
Other names 2-Butoxyethanol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:111-76-2 SDS

111-76-2Synthetic route

ethene
74-85-1

ethene

butan-1-ol
71-36-3

butan-1-ol

2-Butoxyethanol
111-76-2

2-Butoxyethanol

Conditions
ConditionsYield
With dihydrogen peroxide Green chemistry;98.5%
oxirane
75-21-8

oxirane

butan-1-ol
71-36-3

butan-1-ol

2-Butoxyethanol
111-76-2

2-Butoxyethanol

Conditions
ConditionsYield
With aluminum tri-n-butoxide; acetic acid at 170℃; for 24h; Reagent/catalyst; Autoclave;97.75%
With MCM-41-500 ° C catalyst at 100℃; for 4h; Reagent/catalyst; Temperature; Autoclave; High pressure;86.8%
In dodecane at 100℃; Kinetics;
oxirane
75-21-8

oxirane

butan-1-ol
71-36-3

butan-1-ol

A

2-Butoxyethanol
111-76-2

2-Butoxyethanol

B

Diethylene glycol monobutyl ether
112-34-5

Diethylene glycol monobutyl ether

Conditions
ConditionsYield
With potassium aluminum sulfate at 170℃; for 24h; Reagent/catalyst; Autoclave;A 93.1%
B 6.63%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

2-Butoxyethanol
111-76-2

2-Butoxyethanol

Conditions
ConditionsYield
Stage #1: -butyl vinyl ether With borane-ammonia complex In tetrahydrofuran at 90℃; for 3h;
Stage #2: With dihydrogen peroxide; sodium hydroxide In tetrahydrofuran at 0 - 20℃; for 3h;
59%
[1,3]-dioxolan-2-one
96-49-1

[1,3]-dioxolan-2-one

sodium butanolate
2372-45-4

sodium butanolate

2-Butoxyethanol
111-76-2

2-Butoxyethanol

Conditions
ConditionsYield
With benzene at 100℃;
[1,3]-dioxolan-2-one
96-49-1

[1,3]-dioxolan-2-one

butan-1-ol
71-36-3

butan-1-ol

2-Butoxyethanol
111-76-2

2-Butoxyethanol

Conditions
ConditionsYield
With dimethyl sulfate at 130℃;
1,1-bis-(2-methoxy-ethoxy)-butane
71808-63-4

1,1-bis-(2-methoxy-ethoxy)-butane

A

2-Butoxyethanol
111-76-2

2-Butoxyethanol

B

1-(2-methoxy-ethoxy)-butane
13343-98-1

1-(2-methoxy-ethoxy)-butane

Conditions
ConditionsYield
With nickel at 200 - 240℃; under 51485.6 - 77228.3 Torr; Hydrogenation;
Methyl butoxyacetate
10228-54-3

Methyl butoxyacetate

2-Butoxyethanol
111-76-2

2-Butoxyethanol

Conditions
ConditionsYield
With ethanol; copper oxide-chromium oxide at 200℃; under 147102 Torr; Hydrogenation;
butyl butoxyacetate
10397-22-5

butyl butoxyacetate

2-Butoxyethanol
111-76-2

2-Butoxyethanol

Conditions
ConditionsYield
With copper-chromium-iron at 280℃; under 95616 Torr; Hydrogenation;
ethylene glycol
107-21-1

ethylene glycol

2-Butoxyethanol
111-76-2

2-Butoxyethanol

Conditions
ConditionsYield
With sodium und anschliessenden Erhitzen mit 1-Brom-butan;
n-Butyl chloride
109-69-3

n-Butyl chloride

ethylene glycol
107-21-1

ethylene glycol

A

2-Butoxyethanol
111-76-2

2-Butoxyethanol

B

1,2-dibutoxyethane
112-48-1

1,2-dibutoxyethane

Conditions
ConditionsYield
(i) DMSO, NaOH, (ii) /BRN= 1730909/; Multistep reaction;
2-propyl-1,3-dioxolane
3390-13-4

2-propyl-1,3-dioxolane

2-Butoxyethanol
111-76-2

2-Butoxyethanol

Conditions
ConditionsYield
With lithium aluminium tetrahydride; boron trichloride 1.) CH2Cl2, 0.2 h, 2.) Et2O, 30 min; Yield given. Multistep reaction;
In ethylene glycol
With hydrogen; 0.6 wt % palladium on alumina at 210℃; under 16274.9 Torr; Product distribution / selectivity;
2-propyl-1,3-dioxolane
3390-13-4

2-propyl-1,3-dioxolane

A

2-Butoxyethanol
111-76-2

2-Butoxyethanol

B

ethylene glycol
107-21-1

ethylene glycol

Conditions
ConditionsYield
With lithium aluminium tetrahydride; boron trichloride 1.) CH2Cl2, 0.2 h, 2.) Et2O, 30 min; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
2-ethoxy-ethanol
110-80-5

2-ethoxy-ethanol

1-butyl-1-nitrosourea
869-01-2

1-butyl-1-nitrosourea

A

butyl ethyl ether
628-81-9

butyl ethyl ether

B

2-Butoxyethanol
111-76-2

2-Butoxyethanol

C

1-(2-Ethoxyethoxy)butan
4413-13-2

1-(2-Ethoxyethoxy)butan

D

ethylene glycol sec-butyl ethyl ether
77078-19-4

ethylene glycol sec-butyl ethyl ether

Conditions
ConditionsYield
With potassium carbonate Ambient temperature; Further byproducts given;A 2.7 % Chromat.
B 1.8 % Chromat.
C 83.2 % Chromat.
D 11.6 % Chromat.
With sodium hydrogencarbonate for 24h; Ambient temperature; Further byproducts given;A 1.3 % Chromat.
B 2.9 % Chromat.
C 81.9 % Chromat.
D 12.6 % Chromat.
2-ethoxy-ethanol
110-80-5

2-ethoxy-ethanol

1-butyl-1-nitrosourea
869-01-2

1-butyl-1-nitrosourea

A

2-Butoxyethanol
111-76-2

2-Butoxyethanol

B

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

C

1-(2-Ethoxyethoxy)butan
4413-13-2

1-(2-Ethoxyethoxy)butan

D

ethylene glycol sec-butyl ethyl ether
77078-19-4

ethylene glycol sec-butyl ethyl ether

Conditions
ConditionsYield
With sodium hydrogencarbonate for 24h; Ambient temperature; Further byproducts given;A 2.9 % Chromat.
B 0.9 % Chromat.
C 81.9 % Chromat.
D 12.6 % Chromat.
butyl butoxyacetate
10397-22-5

butyl butoxyacetate

Cu-Cr-Fe-catalyst

Cu-Cr-Fe-catalyst

2-Butoxyethanol
111-76-2

2-Butoxyethanol

Conditions
ConditionsYield
at 280℃; under 95616 Torr; Anfangsdruck.Hydrogenation;
1-iodo-butane
542-69-8

1-iodo-butane

monosodium compound of ethylene glycol

monosodium compound of ethylene glycol

2-Butoxyethanol
111-76-2

2-Butoxyethanol

formaldehyde-<2-butyloxy-ethylacetal>

formaldehyde-<2-butyloxy-ethylacetal>

A

2-Butoxyethanol
111-76-2

2-Butoxyethanol

B

1-(2-methoxy-ethoxy)-butane
13343-98-1

1-(2-methoxy-ethoxy)-butane

Conditions
ConditionsYield
With nickel at 200 - 240℃; under 51485.6 - 77228.3 Torr; Hydrogenation;
2-methoxy-ethanol
109-86-4

2-methoxy-ethanol

1-butyl-1-nitrosourea
869-01-2

1-butyl-1-nitrosourea

A

1,2-dimethoxyethane
110-71-4

1,2-dimethoxyethane

B

butyl methyl ether
628-28-4

butyl methyl ether

C

2-Butoxyethanol
111-76-2

2-Butoxyethanol

D

2-(1-Methylpropoxy)ethanol
7795-91-7

2-(1-Methylpropoxy)ethanol

E

1-(2-methoxy-ethoxy)-butane
13343-98-1

1-(2-methoxy-ethoxy)-butane

F

2-(2-Methoxyethoxy)butan

2-(2-Methoxyethoxy)butan

G

butenes, butanols, sBuOMe

butenes, butanols, sBuOMe

Conditions
ConditionsYield
With potassium carbonate for 0.0833333h; Product distribution; Mechanism; Ambient temperature; further reagent: NaHCO3, further reactions with EtOCH2CH2OH, MeOH-oxirane, -oxetane, -tetrahydrofuran;A 0.5 % Chromat.
B 2.9 % Chromat.
C 7.2 % Chromat.
D 0.5 % Chromat.
E 74.4 % Chromat.
F 14.2 % Chromat.
G n/a
oxirane
75-21-8

oxirane

butan-1-ol
71-36-3

butan-1-ol

A

2-Butoxyethanol
111-76-2

2-Butoxyethanol

B

Diethylene glycol monobutyl ether
112-34-5

Diethylene glycol monobutyl ether

C

triethyleneglycol monobutyl ether
143-22-6

triethyleneglycol monobutyl ether

Conditions
ConditionsYield
2,4,6-trimethyl-pyridine at 160℃; under 2311.54 - 3345.86 Torr; for 2.5h; Product distribution / selectivity; Inert atmosphere;
sodium butanolate at 140℃; under 7500.75 Torr; for 5h; Product distribution / selectivity;A 20.16 %Chromat.
B 9.07 %Chromat.
C 6.10 %Chromat.
catalyst of invention (Sb2O3, copper acetate, hydrogen peroxide; calcined) at 140℃; under 30003 Torr; for 24 - 120h; Product distribution / selectivity;A 76 - 77 %Chromat.
B 13 - 14 %Chromat.
C 9 %Chromat.
di-n-butyloxymethane
2568-90-3

di-n-butyloxymethane

2-Butoxyethanol
111-76-2

2-Butoxyethanol

Ru3 (CO)12

Ru3 (CO)12

HCCo(CO)9

HCCo(CO)9

Dimethoxymethane
109-87-5

Dimethoxymethane

2-Butoxyethanol
111-76-2

2-Butoxyethanol

Conditions
ConditionsYield
With carbon monoxide; hydrogen In butan-1-ol
butan-1-ol
71-36-3

butan-1-ol

2-Butoxyethanol
111-76-2

2-Butoxyethanol

Conditions
ConditionsYield
With hydrogen; paraformaldehyde
diphenyl sulfide
139-66-2

diphenyl sulfide

butan-1-ol
71-36-3

butan-1-ol

2-Butoxyethanol
111-76-2

2-Butoxyethanol

Conditions
ConditionsYield
With hydrogen; paraformaldehyde
Tetraethylene glycol
112-60-7

Tetraethylene glycol

ethylene glycol
107-21-1

ethylene glycol

butyraldehyde
123-72-8

butyraldehyde

diethylene glycol
111-46-6

diethylene glycol

2,2'-[1,2-ethanediylbis(oxy)]bisethanol
112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

A

2-propyl-1,3-dioxolane
3390-13-4

2-propyl-1,3-dioxolane

B

2-Butoxyethanol
111-76-2

2-Butoxyethanol

C

Diethylene glycol monobutyl ether
112-34-5

Diethylene glycol monobutyl ether

D

triethyleneglycol monobutyl ether
143-22-6

triethyleneglycol monobutyl ether

E

tetraethylene glycol monobutyl ether
1559-34-8

tetraethylene glycol monobutyl ether

F

butan-1-ol
71-36-3

butan-1-ol

Conditions
ConditionsYield
With hydrogen; palladium 10% on activated carbon at 180℃; under 51716.2 Torr; for 2h;
ethylene glycol
107-21-1

ethylene glycol

butyraldehyde
123-72-8

butyraldehyde

A

2-Butoxyethanol
111-76-2

2-Butoxyethanol

B

butan-1-ol
71-36-3

butan-1-ol

Conditions
ConditionsYield
With hydrogen; palladium 10% on activated carbon at 180℃; under 51716.2 Torr; for 2h; Product distribution / selectivity; Inert atmosphere;A 88.7 %Chromat.
B 7.2 %Chromat.
With hydrogen; 5%-palladium/activated carbon at 200℃; under 25877.6 Torr; for 1h; Autoclave;
With palladium 10% on activated carbon; hydrogen at 180℃; under 51755.2 Torr; for 2h; Temperature; Concentration;A 88.7 %Chromat.
B 7.2 %Chromat.
ethylene glycol
107-21-1

ethylene glycol

butyraldehyde
123-72-8

butyraldehyde

A

2-Butoxyethanol
111-76-2

2-Butoxyethanol

B

1,2-dibutoxyethane
112-48-1

1,2-dibutoxyethane

C

butan-1-ol
71-36-3

butan-1-ol

Conditions
ConditionsYield
With hydrogen; palladium 10% on activated carbon at 180℃; under 51716.2 Torr; for 2h; Product distribution / selectivity; Inert atmosphere;A 79.7 %Chromat.
B 7.7 %Chromat.
C 7.5 %Chromat.
With palladium 10% on activated carbon; hydrogen at 180℃; under 51755.2 Torr; for 2h;A 79.7 %Chromat.
B 7.7 %Chromat.
C 7.5 %Chromat.
ethylene glycol
107-21-1

ethylene glycol

butyraldehyde
123-72-8

butyraldehyde

2-Butoxyethanol
111-76-2

2-Butoxyethanol

Conditions
ConditionsYield
With hydrogen; palladium 10% on activated carbon at 180℃; under 25858.1 Torr; for 3h; Product distribution / selectivity; Inert atmosphere;85.5 %Chromat.
With palladium 10% on activated carbon; hydrogen at 180℃; under 26252.6 Torr; for 3h;85.5 %Chromat.

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Adsorption of hydraulic fracturing fluid components 2-Butoxyethanol (cas 111-76-2) and furfural onto granular activated carbon and shale rock08/26/2019

The objective of this study was to understand the adsorption ability of a surfactant and a non-surfactant chemical additive used in hydraulic fracturing onto shale and GAC. Experiments were performed at varying temperatures and sodium chloride concentrations to establish these impacts on the ads...detailed

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The removal of 2-butoxyethanol from gaseous emissions was studied using two biotrickling filters (BTF1 and BTF2) packed with polyurethane foam. Two different inoculum sources were used: a pure culture of Pseudomonas sp. BOE200 (BTF1) and activated sludge from a municipal wastewater treatment pla...detailed

Degradation of hydraulic fracturing additive 2-Butoxyethanol (cas 111-76-2) using heat activated persulfate in the presence of shale rock08/23/2019

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Extraction and recovery of 2-Butoxyethanol (cas 111-76-2) from aqueous phases containing high saline concentration08/21/2019

Ethylene glycol monobutyl ether (EGBE), also known as 2-butoxyethanol (2-BE), has been identified as a contaminant in hydraulic fracturing fluids. In order to determine the presence of 2-BE in hydraulic fracturing chemical additives, a reliable method for recovering 2-BE from aqueous phases by l...detailed

Role of SULT-mediated sulfation in the biotransformation of 2-Butoxyethanol (cas 111-76-2) and sorbitan monolaurate: A study using zebrafish SULTs08/20/2019

2-Butoxyethanol and sorbitan monolaurate are major components of oil dispersants that are applied in large quantities to control oil spill in the aquatic environment. An important question is whether aquatic animals are equipped with mechanisms for the detoxification of these oil dispersant comp...detailed

111-76-2Relevant articles and documents

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Letsinger,R.L.,McLean,D.B.

, p. 2230 - 2236 (1963)

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OPEN-FLASK HYDROBORATION AND THE USE THEREOF

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Paragraph 0046; 0058; 0059, (2018/03/25)

The present disclosure generally relates to a process for hydroboration of an alkene or alkyne using ammonia borane (AB). In particular, the present invention relates to hydroboration of an alkene or alkyne in the presence of air or moisture, and a clean process for facile preparation of an alcohol by oxidizing the organoborane so formed with hydrogen peroxide. The products, including aminodialkylboranes, ammonia trialkylborane complexes, as well as various alcohols so prepared, are within the scope of this disclosure.

Preparation method of ethylene glycol monobutyl ether

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Paragraph 0019; 0021, (2017/07/18)

The invention relates to the field of chemistry and chemical engineering and particularly discloses a preparation method of ethylene glycol monobutyl ether. The preparation method of the ethylene glycol monobutyl ether is characterized in that ethylene oxide and n-butyl alcohol are prepared into a raw material mixed solution, and cold storage is performed for usage; high-silicon-content alloy or an all-silicon molecular sieve and porous silicon dioxide are put in a muffle furnace to perform high-temperature roasting, and a roasting catalyst is put in a dryer for usage after being numbered; the raw material solution and the roasting catalyst are put in a reaction kettle for reaction, and a product is obtained. The high-silicon-content alloy or the all-silicon molecular sieve and the porous silicon dioxide used by the method is low in procurement cost, the treating process is simple, a production process is greatly simplified, the production cost is reduced, the catalyst or ethylene glycol butyl ether is high in selectivity, and the preparation method has very high stability.

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