318957-41-4

Upstream product

• 244177-70-6 (4S,5R)-3-((2S,3R)-2-isobutyl-3-hydroxypent-4-enoyl)-4-methyl-5-phenyl-1,3-oxazolidin-2-on 
• 168540-62-3 (4S,5R)-3-(4-methylpentanoyl)-4-methyl-5-phenyl-1,3-oxazolidin-2-on 
• 318957-32-3 (2R,3S)-3-hydroxy-2-isobutylpent-4-enethioic acid S-benzyl ester 
• 134458-52-9 (4R,5S)-4-methyl-3-(4-methylpentanoyl)-5-phenyl-oxazolidin-2-one 
• 52791-97-6 lithium phenylmethanethiolate 
• 38136-29-7 4-methylvaleroyl chloride 
• 227293-93-8 (4R,5S)-3-((2R,3S)-3-Hydroxy-2-isobutyl-pent-4-enoyl)-4-methyl-5-phenyl-oxazolidin-2-one 
• 318957-89-0 (2R,3S)-3-(tert-butyldimethylsilanyloxy)-2-isobutylpent-4-enoic acid 
• 75-78-5 dimethylsilicon dichloride 
• 244177-72-8 (2S,3R)-3-hydroxy-2-isobutylpent-4-enethioic acid S-benzyl ester 
• 318957-33-4 (1R,2S)-(2-hydroxy-1-isobutylbut-3-enyl)-carbamic acid 9H-fluoren-9-ylmethyl ester 

Downstream Products

• 318957-56-1 (2S,3R,6S,7R)-7-(9H-fluoren-9-ylmethoxycarbonylamino)-3,6-dihydroxy-2-isobutyl-9-methyldec-4-enethioic acid S-benzyl ester 

Relevant academic research and scientific papers

A modular synthetic approach toward exhaustively stereodiversified ligand libraries

(Matrix presented) This report describes a modular approach to the synthesis of stereodiversified natural product-like libraries. Monomers 2 and 3 were coupled in parallel by silyl-tethered olefin metathesis to generate all 16 stereoisomers of cis-enediol