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Benzenemethanethiol, lithium salt, also known as lithium benzyl mercaptide, is a chemical compound with the molecular formula C7H7LiS. It is a colorless to pale yellow solid, soluble in water and organic solvents, and is commonly used as a reagent in organic synthesis, particularly in the formation of carbon-carbon bonds and the reduction of various functional groups. This lithium salt is derived from benzenemethanethiol, where a hydrogen atom is replaced by a lithium atom, enhancing its reactivity and making it a valuable intermediate in the synthesis of pharmaceuticals, agrochemicals, and other specialty chemicals.

52791-97-6

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52791-97-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 52791-97-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,2,7,9 and 1 respectively; the second part has 2 digits, 9 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 52791-97:
(7*5)+(6*2)+(5*7)+(4*9)+(3*1)+(2*9)+(1*7)=146
146 % 10 = 6
So 52791-97-6 is a valid CAS Registry Number.

52791-97-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name lithium phenylmethanethiolate

1.2 Other means of identification

Product number -
Other names lithium benzylthiolate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:52791-97-6 SDS

52791-97-6Relevant academic research and scientific papers

The synthesis and structure of a thiobenzyl-functionalized dibenzoferrocene complex

Curnow, Owen J.,Shang, Rong

, p. 2790 - 2799 (2010)

3-(Thiobenzyl)indene (2) was prepared from lithium indenide and dibenzyl disulfide. Deprotonation with BuLi/TMEDA in THF and the addition of FeCl 2 gave the expected 1: 1 mixture of rac-and meso-bis(1- thiobenzylindenyl)iron(II) (3). 13C-NMR studies in THF suggest that 3 undergoes a ring-flipping process to interconvert rac-and meso-3. Complex 3 exhibits a reversible cyclic voltammogram with an oxidation potential of-177 mV versus the Fc/Fc+ couple in dichloromethane. Indene (2) and ferrocene (3) were also characterised by X-ray crystallography.

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