31928-99-1Relevant articles and documents
Ionic liquid supported on magnetic nanoparticles as highly efficient and recyclable catalyst for the synthesis of β-keto enol ethers
Li, Pei-He,Li, Bao-Le,Hu, Hai-Chuan,Zhao, Xiao-Na,Zhang, Zhan-Hui
, p. 118 - 122 (2014/01/17)
A magnetically ionic liquid supported on γ-Fe2O 3 nanocatalyst (AlxCly-IL-SiO 2γ-Fe2O3) was synthesized and evaluated as a recoverable catalyst for the synthesis of β-keto enol ethers. The immobilized catalyst proved to be effective and provided the products in high to excellent yield at room temperature. Moreover, the catalyst could be easily recovered by magnetic separation and recycled for six times without significant loss of its catalytic activity.
Zinc-mediated alkylation and acylation of 1,3-dicarbonyl compounds
Yadav,Reddy, B. V. Subba,Mishra, Anand Kumar
experimental part, p. 280 - 281 (2010/09/05)
1,3-Dicarbonyl compounds undergo smooth allylation, benzylation, propargylation, and acylation with halides using metallic zinc in DMF at 60 °C to afford the corresponding allyl, benzyl, 2-propynyl, and acylated 1,3-diesters in good yields. In the case of cyclic 1,3-diketones, the corresponding enol ethers are obtained as sole products instead of C-alkylation.
Cerium(IV) ammonium nitrate-catalyzed synthesis of β-keto enol ethers from cyclic β-diketones and their deprotection
Banerjee, Biplab,Mandal, Samir Kumar,Roy, Subhas Chandra
, p. 16 - 17 (2007/10/03)
A mild and efficient method for etherification of cyclic β-diketones with alcohols has been developed using a catalytic amount of cerium(IV) ammonium nitrate at room temperature to afford the corresponding β-keto enol ethers in good to excellent yields. The deprotections of enol ethers in water-acetonitrile (1:1) using a catalytic amount (10 mol %) of cerium(IV) ammonium nitrate have also been achieved. Copyright
