32040-09-8

Basic information

• Product Name: 4-(3-Methoxyphenyl)morpholine
• Synonyms: 4-(3-Methoxyphenyl)morpholine
• CAS NO: 32040-09-8
• Molecular Formula: C₁₁H₁₅NO₂
• Molecular Weight: 193.24
• Product Categories: pharmacetical
• Mol File: 32040-09-8.mol
• Article Data: 80

Chemical Properties

• Boiling Point: 333.2°Cat760mmHg
• Flash Point: 140°C
• Appearance: /
• Density: 1.093g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.532
• PKA: 4.77±0.40(Predicted)
• CAS DataBase Reference: 4-(3-Methoxyphenyl)morpholine(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(3-Methoxyphenyl)morpholine(32040-09-8)
• EPA Substance Registry System: 4-(3-Methoxyphenyl)morpholine(32040-09-8)

Safety Data

• Hazardous Substances Data: 32040-09-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C11H15NO2/c1-13-11-4-2-3-10(9-11)12-5-7-14-8-6-12/h2-4,9H,5-8H2,1H3

Upstream product

• 6986-48-7 bis-1-chloroethyl ether 
• 536-90-3 m-Anisidine 
• 27292-49-5 3-(4-morpholino)phenol 
• 80-48-8 methyl p-toluene sulfonate 
• 110-91-8 morpholine 
• 3908-66-5 tris(3-methoxyphenyl) phosphate 
• 110-89-4 piperidine 
• 2845-89-8 1-chloro-3-methoxy-benzene 
• 111-92-2 dibutylamine 
• 108-90-7 chlorobenzene 
• 5765-65-1 4-(benzoyloxy)morpholine 
• 53392-03-3 (3-methoxyphenyl)triethoxysilane 
• 331-64-6 2-fluoro-4-methoxy-benzaldehyde 
• 578-57-4 2-bromoanisole 

Downstream Products

• 96649-02-4 2-methoxy-6-(1-morpholinyl)benzaldehyde 
• 1032716-22-5 4-(3-Methoxy-4-nitrosophenyl)morpholine 
• 68659-82-5 4-(5-methoxy-cyclohexa-1,4-dienyl)-morpholine 

Relevant articles and documents

Product selective reaction controlled by the combination of palladium nanoparticles, continuous microwave irradiation, and a co-existing solid; ligand-free Buchwald-Hartwig aminationvs.aryne amination

We have developed a continuous microwave irradiation-assisted Buchwald-Hartwig amination using our original Pd nanoparticle catalyst with a copper plate as a co-existing metal solid. In this methodology, a microwave-controlled product selectivity was achieved between Buchwald-Hartwig amination and aryne amination performed under strongly basic conditions and at a high reaction temperature, because a polar chemical species such as Ar-Pd-halogen might be activated selectively by microwave radiation. Moreover, our catalyst could be used repeatedly over 10 times, and the amount of Pd leaching could be suppressed to a low level.

Coupling of Alternating Current to Transition-Metal Catalysis: Examples of Nickel-Catalyzed Cross-Coupling

The coupling of transition-metal to photoredox catalytic cycles through single-electron transfer steps has become a powerful tool in the development of catalytic processes. In this work, we demonstrated that transition-metal catalysis can be coupled to al

Photo-induced dealdehyding method

The invention provides a photo-induced dealdehyding method, and belongs to the technical field of organic synthesis. The photo-induced dealdehyding method comprises the following steps that a mixtureof a compound shown in the formula I and a solvent are reacted under an inert gas atmosphere and visible light irradiation, a dealdehyding product is obtained, and no photocatalyst is used in the whole process; wherein the structural formula of the formula I shown in the specification, R is a functional group and is selected from hydrogen, methyl, methoxyl, cyano, chlorine, bromine or fluorine. According to the photo-induced dealdehyding method, in the inert gas atmosphere, the compound shown in the formula (I) can be excited to generate carbon-oxygen bond homogeneous cracking through visiblelight irradiation, then free radical migration and double bond displacement are conducted, finally carbon monoxide is removed, aldehyde group removal is completed, no photocatalyst is needed in the whole process, operation is easy and convenient, and conditions are mild.