32058-60-9Relevant articles and documents
Samarium(III) triflate: A new catalyst for facile synthesis of benzothiazoles and benzoxazoles from carboxylic acids in aqueous media
Gorepatil, Pratapsinha B.,Mane, Yogesh D.,Gorepatil, Amarsinha B.,Gaikwad, Mahadev V.,Ingle, Vilas S.
, p. 8355 - 8362 (2015/10/20)
A facile synthetic method for benzothiazoles and benzoxazoles comprising the reaction of corresponding 2-aminothiophenol and 2-aminophenol with various substituted aromatic carboxylic acids using Samarium(III) triflate as a catalyst has been described. The advantages of the method are short reaction times and aqueous reaction media and easy work-up. The catalysts can be recovered for the subsequent reactions and reused without any appreciable loss of efficiency.