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4-Chloro-3-nitrobenzoic acid Manufacturer/High quality/Best price/In stock
Cas No: 96-99-1
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
High quality 4-Chloro-3-Nitro-Benzoic Acid supplier in China
Cas No: 96-99-1
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4-chloro-3-nitrobenzoic Acid
Cas No: 96-99-1
USD $ 1.0-2.0 / Metric Ton 1 Metric Ton 500 Metric Ton/Week Hebei yanxi chemical co.,LTD. Contact Supplier
4-Chloro-3-nitrobenzoic acid
Cas No: 96-99-1
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4-Chloro-3-nitrobenzoic acid
Cas No: 96-99-1
USD $ 2.0-3.0 / Kilogram 1 Kilogram 20 Metric Ton/Day EAST CHEMSOURCES LIMITED Contact Supplier
4-chloro-3-nitrobenzoate
Cas No: 96-99-1
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4-Chloro-3-nitrobenzoic acid
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4-Chloro-3-nitrobenzoic acid
Cas No: 96-99-1
USD $ 5.0-5.0 / Kilogram 1 Kilogram 1000 Kilogram/Month Enke Pharma-tech Co.,Ltd. (Cangzhou, China ) Contact Supplier
4-Chloro-3-nitrobenzoic acid
Cas No: 96-99-1
USD $ 1.0-1.0 / Kilogram 1 Kilogram 2000 Metric Ton/Year Henan Sinotech Import&Export Corporation Contact Supplier
TIANFUCHEM--96-99-1--4-Chloro-3-nitrobenzoic acid factory price
Cas No: 96-99-1
USD $ 2000.0-2000.0 / Metric Ton 1 Metric Ton 1000 Metric Ton/Day Henan Tianfu Chemical Co., Ltd. Contact Supplier

96-99-1 Usage

Chemical Properties

white to light yellow crystal powder
InChI:InChI=1/C7H4ClNO4/c8-5-2-1-4(7(10)11)3-6(5)9(12)13/h1-3H,(H,10,11)/p-1

96-99-1 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (A12807)  4-Chloro-3-nitrobenzoic acid, 99%    96-99-1 5000g 7172.0CNY Detail
Alfa Aesar (A12807)  4-Chloro-3-nitrobenzoic acid, 99%    96-99-1 1000g 1723.0CNY Detail
Alfa Aesar (A12807)  4-Chloro-3-nitrobenzoic acid, 99%    96-99-1 500g 918.0CNY Detail
Alfa Aesar (A12807)  4-Chloro-3-nitrobenzoic acid, 99%    96-99-1 100g 234.0CNY Detail

96-99-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-Chloro-3-nitrobenzoic Acid

1.2 Other means of identification

Product number -
Other names 4-Chloro-3-nitrobenzoic acid

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:96-99-1 SDS

96-99-1Synthetic route

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
With sulfuric acid; nitric acid In dichloromethane; water97.3%
With sulfuric acid; nitric acid at 30 - 35℃; for 6h;97.56%
With nitric acid for 1h; Heating;85%
4-chloro-3-nitro-benzaldehyde
16588-34-4

4-chloro-3-nitro-benzaldehyde

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
With copper(II) oxide; dihydrogen peroxide In acetonitrile at 60℃; for 5h; Green chemistry;82%
With permanganate(VII) ion
4-chloro-3-nitrobenzonitrile
939-80-0

4-chloro-3-nitrobenzonitrile

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
With sulfuric acid
With nitric acid
4-n-butanoyl-2-nitrochlorobenzene
66353-38-6

4-n-butanoyl-2-nitrochlorobenzene

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
With chromium(III) oxide; sulfuric acid
1-chloro-4-methyl-2-nitro-benzene
89-60-1

1-chloro-4-methyl-2-nitro-benzene

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

1-chloro-4-(chloromethyl)-2-nitrobenzene
57403-35-7

1-chloro-4-(chloromethyl)-2-nitrobenzene

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
With potassium permanganate
4-Chloro-3-nitro-benzoic acid 4-nitro-phenyl ester
193606-98-3

4-Chloro-3-nitro-benzoic acid 4-nitro-phenyl ester

A

p-nitrophenolate
14609-74-6

p-nitrophenolate

B

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
With hydroxide In water; dimethyl sulfoxide at 25℃; Rate constant; for determination of Hammett plot;
With sodium hydroxide In water; dimethyl sulfoxide at 25℃; Kinetics;
sulfuric acid
7664-93-9

sulfuric acid

nitric acid
7697-37-2

nitric acid

para-chloroacetophenone
99-91-2

para-chloroacetophenone

A

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

B

1-<4-chloro-3-nitro-phenyl>-ethanone-(1)

1-<4-chloro-3-nitro-phenyl>-ethanone-(1)

Conditions
ConditionsYield
at -12 - -10℃;
1-<4-chloro-3-nitro-phenyl>-ethanone-(1)

1-<4-chloro-3-nitro-phenyl>-ethanone-(1)

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
With potassium permanganate; water; magnesium sulfate
sulfuric acid
7664-93-9

sulfuric acid

2-chloro-3-nitro-5-trifluoromethylbenzene
121-17-5

2-chloro-3-nitro-5-trifluoromethylbenzene

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

4-n-butanoyl-2-nitrochlorobenzene
66353-38-6

4-n-butanoyl-2-nitrochlorobenzene

diluted Cr2O3-H2SO4

diluted Cr2O3-H2SO4

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

1-chloro-4-(2-chloro-propyl)-2-nitro-benzene

1-chloro-4-(2-chloro-propyl)-2-nitro-benzene

KMnO4

KMnO4

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

3-nitro-4-sulfo-benzoic acid
439693-71-7

3-nitro-4-sulfo-benzoic acid

A

3,4-dichlorbenzoic acid
51-44-5

3,4-dichlorbenzoic acid

B

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
at 180 - 200℃; Kochen des Produktes mit Wasser;
[4-(4-chloro-3-nitro-benzoylamino)-3-nitro-phenyl]-arsonic acid
861789-63-1

[4-(4-chloro-3-nitro-benzoylamino)-3-nitro-phenyl]-arsonic acid

diluted NaOH-solution

diluted NaOH-solution

A

3-nitro-4-hydroxybenzoic acid
616-82-0

3-nitro-4-hydroxybenzoic acid

B

(4-amino-3-nitro-phenyl)-arsonic acid
5440-06-2

(4-amino-3-nitro-phenyl)-arsonic acid

C

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

4-(4-chloro-3-nitrophenyl)-4-oxobutanoic acid
84314-04-5

4-(4-chloro-3-nitrophenyl)-4-oxobutanoic acid

A

malonic acid
141-82-2

malonic acid

B

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
With sodium hydroxide; sodium hydrogencarbonate; sodium carbonate; potassium hexacyanoferrate(III); osmium(VIII) oxide In water at 36.85℃; Activation energy;
2,4-dinitrophenyl 4-chloro-3-nitrobenzoate

2,4-dinitrophenyl 4-chloro-3-nitrobenzoate

A

2,4-dinitrophenolate
20350-26-9

2,4-dinitrophenolate

B

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
With hydroxide In water; dimethyl sulfoxide at 25℃; Kinetics; Alkaline hydrolysis;
4-Chloro-3-nitroaniline
635-22-3

4-Chloro-3-nitroaniline

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: durch Austausch von NH2 gegen CN nach Sandmeyer
2: concentrated sulfuric acid
View Scheme
4-n-butanoylchlorobenzene
4981-63-9

4-n-butanoylchlorobenzene

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: HNO3+H2SO4 / <-5
2: Cr2O3-H2SO4
View Scheme
2-Chloronitrobenzene
88-73-3

2-Chloronitrobenzene

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sulfuric acid; hydrogen chloride / 85 °C
2: aqueous KMnO4
View Scheme
Multi-step reaction with 2 steps
1: H2SO4; paraformaldehyde; HCl / 85 °C
2: aqueous KMnO4
View Scheme
chlorobenzene
108-90-7

chlorobenzene

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: aluminium chloride / 40 - 60 °C
2: HNO3+H2SO4 / <-5
3: Cr2O3-H2SO4
View Scheme
4-Cyanochlorobenzene
623-03-0

4-Cyanochlorobenzene

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: nitric acid
2: aqueous nitric acid
View Scheme
para-chlorotoluene
106-43-4

para-chlorotoluene

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sodium dichromate; aqueous sulfuric acid; acetic acid
2: nitric acid
View Scheme
Multi-step reaction with 2 steps
1: nitric acid / 70 °C
2: nitric acid / 50 °C
View Scheme
4-chloro-3-nitrobenzamide
16588-06-0

4-chloro-3-nitrobenzamide

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: phosphorus oxychloride / 170 °C
2: aqueous nitric acid
View Scheme
4-chloro-3-nitro-benzoyl chloride
38818-50-7

4-chloro-3-nitro-benzoyl chloride

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: tetrachloromethane; aqueous ammonia
2: phosphorus oxychloride / 170 °C
3: aqueous nitric acid
View Scheme
Multi-step reaction with 3 steps
1: triethylamine / diethyl ether
2: hydrogenchloride / water; acetonitrile
3: water; dimethyl sulfoxide / 25 °C
View Scheme
concentrated H2 SO4

concentrated H2 SO4

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
With Concentrated HNO3
C6H3N2O5(1-)*C12H9ClN3O3(1+)

C6H3N2O5(1-)*C12H9ClN3O3(1+)

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
With water; dimethyl sulfoxide at 25℃; Kinetics;
2,4-dinitrophenyl 4-chloro-3-nitrobenzoate

2,4-dinitrophenyl 4-chloro-3-nitrobenzoate

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: hydrogenchloride / water; acetonitrile
2: water; dimethyl sulfoxide / 25 °C
View Scheme
4-nitro-phenol
100-02-7

4-nitro-phenol

4-chloro-3-nitro-benzoyl chloride
38818-50-7

4-chloro-3-nitro-benzoyl chloride

A

p-nitrophenolate
14609-74-6

p-nitrophenolate

B

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: triethylamine / diethyl ether
2: sodium hydroxide / dimethyl sulfoxide; water / 25 °C
View Scheme
methylamine
74-89-5

methylamine

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

4-(methylamino)-3-nitrobenzoic acid
41263-74-5

4-(methylamino)-3-nitrobenzoic acid

Conditions
ConditionsYield
In water at 100℃; for 14h;100%
In water at 80℃; for 5h;100%
Stage #1: methylamine; 4-chloro-3-nitrobenzoate In water for 4h; Reflux;
Stage #2: With sulfuric acid In water at 20℃; pH=2; Product distribution / selectivity;
95.5%
ethanol
64-17-5

ethanol

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

ethyl 4-chloro-3-nitrobenzoate
16588-16-2

ethyl 4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
With sulfuric acid for 4h; Heating;100%
With thionyl chloride for 2.25h; Heating / reflux;96%
With hydrogenchloride Heating;95%
ethyl iodide
75-03-6

ethyl iodide

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

ethyl 4-chloro-3-nitrobenzoate
16588-16-2

ethyl 4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 60℃; for 3h;100%
Stage #1: 4-chloro-3-nitrobenzoate With potassium carbonate In DMF (N,N-dimethyl-formamide) for 0.5h;
Stage #2: ethyl iodide In DMF (N,N-dimethyl-formamide) at 50℃; for 4h;
86%
Stage #1: 4-chloro-3-nitrobenzoate With potassium carbonate In DMF (N,N-dimethyl-formamide) for 0.5h;
Stage #2: ethyl iodide In DMF (N,N-dimethyl-formamide) at 50℃; for 4h;
86%
ethylamine
75-04-7

ethylamine

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

4-(ethylamino)-3-nitrobenzoic acid
2788-74-1

4-(ethylamino)-3-nitrobenzoic acid

Conditions
ConditionsYield
In water at 80℃; for 5h;100%
at 70℃; for 5h;99%
In water at 80℃;95%
methanol
67-56-1

methanol

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

methyl 3-nitro-4-chlorobenzoate
14719-83-6

methyl 3-nitro-4-chlorobenzoate

Conditions
ConditionsYield
With sulfuric acid for 16h; Reflux;98%
With sulfuric acid at 80℃;98%
With hydrogenchloride Heating;97%
4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

3-nitro-4-hydroxybenzoic acid
616-82-0

3-nitro-4-hydroxybenzoic acid

Conditions
ConditionsYield
With water; sodium hydroxide at 100℃;98%
With sodium hydroxide In water at 95℃; for 10h;91.83%
With sodium hydroxide In water430 g (90 %)
6a-hydroxy-artemisinin

6a-hydroxy-artemisinin

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

C22H24ClNO9

C22H24ClNO9

Conditions
ConditionsYield
With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran at 0 - 20℃; for 12h; Inert atmosphere;98%
tert-butylisonitrile
119072-55-8, 7188-38-7

tert-butylisonitrile

benzaldehyde
100-52-7

benzaldehyde

p-aminoiodobenzene
540-37-4

p-aminoiodobenzene

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

N-(2-tert-butylamino)-2-oxo-1-phenylethyl-4-chloro-N-(4-iodophenyl)-3-nitrobenzamide

N-(2-tert-butylamino)-2-oxo-1-phenylethyl-4-chloro-N-(4-iodophenyl)-3-nitrobenzamide

Conditions
ConditionsYield
In methanol at 20℃; for 24h;98%
4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

ethyl 4-chloro-3-nitrobenzoate
16588-16-2

ethyl 4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
With sulfuric acid In ethanol97%
Stage #1: 4-chloro-3-nitrobenzoate With potassium carbonate In DMF (N,N-dimethyl-formamide) for 0.5h;
Stage #2: With ethyl iodide at 50℃; for 4h; Heating / reflux;
86%
Multi-step reaction with 2 steps
1: 95 percent / cerium(IV) ammonium nitrate / 336 h / 20 °C
2: 98 percent / cerium(IV) ammonium nitrate / 144 h / 20 °C
View Scheme
In ethanol
aniline
62-53-3

aniline

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

4-chloro-3-nitro-N-phenylbenzamide
41614-16-8

4-chloro-3-nitro-N-phenylbenzamide

Conditions
ConditionsYield
With thionyl chloride In chlorobenzene at 70 - 100℃; for 2h; Reagent/catalyst; Solvent; Temperature; Large scale; Green chemistry;97%
C15H17NO3

C15H17NO3

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

C22H19ClN2O6

C22H19ClN2O6

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 20℃;97%
4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

4-chloro-3-nitrobenzyl alcohol
55912-20-4

4-chloro-3-nitrobenzyl alcohol

Conditions
ConditionsYield
With borane-THF; boron trifluoride diethyl etherate In tetrahydrofuran at 20℃; for 18h;96%
With borane-THF In tetrahydrofuran at 20℃; for 24h; Inert atmosphere;96%
With dimethylsulfide borane complex In tetrahydrofuran Ambient temperature;95%
4-Benzyloxyphenol
103-16-2

4-Benzyloxyphenol

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

4-(4-benzyloxy-phenoxy)-3-nitro-benzoic acid
943771-70-8

4-(4-benzyloxy-phenoxy)-3-nitro-benzoic acid

Conditions
ConditionsYield
Stage #1: 4-Benzyloxyphenol With potassium hydroxide In dimethyl sulfoxide at 20℃; for 0.166667h;
Stage #2: 4-chloro-3-nitrobenzoate In dimethyl sulfoxide at 120℃; for 1h;
Stage #3: With hydrogenchloride; water In dimethyl sulfoxide at 0℃; pH=3;
96%
propargyl alcohol
107-19-7

propargyl alcohol

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

prop-2-yn-1-yl 4-chloro-3-nitrobenzoate

prop-2-yn-1-yl 4-chloro-3-nitrobenzoate

Conditions
ConditionsYield
With thionyl chloride at -20 - 20℃; for 18h; Inert atmosphere;96%
4-Nitrophenylene-1,2-diamine
99-56-9

4-Nitrophenylene-1,2-diamine

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

2-(4-chloro-3-nitrophenyl)-5-nitro-1H-benzimidazole
1291074-93-5

2-(4-chloro-3-nitrophenyl)-5-nitro-1H-benzimidazole

Conditions
ConditionsYield
With trichlorophosphate for 30h; Reflux;95%
piperidine
110-89-4

piperidine

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

1-(4-chloro-3-nitro-benzoyl)-piperidine
91721-46-9

1-(4-chloro-3-nitro-benzoyl)-piperidine

Conditions
ConditionsYield
Stage #1: 4-chloro-3-nitrobenzoate With 1,1'-carbonyldiimidazole In ethyl acetate at 20℃; for 1h;
Stage #2: piperidine In ethyl acetate at 20℃; for 1h;
95%
piperidine
110-89-4

piperidine

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

3-nitro-4-(piperidin-1-yl)benzoic acid
26586-26-5

3-nitro-4-(piperidin-1-yl)benzoic acid

Conditions
ConditionsYield
With D-myo-inositol; copper; caesium carbonate In water at 100℃;94%
With L-2-O-methyl-chiro-inositol; copper(II) acetate monohydrate; potassium carbonate In dimethyl sulfoxide at 110℃; for 20h; Inert atmosphere;88%
aniline
62-53-3

aniline

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

2-nitrodiphenylamine-4-carboxylic acid
16927-49-4

2-nitrodiphenylamine-4-carboxylic acid

Conditions
ConditionsYield
With potassium carbonate In water at 150℃; for 2h;94%
In propan-1-ol for 12h; Heating;80%
In propan-1-ol for 12h; Reflux;80%
With 4-methyl-morpholine; copper In i-Amyl alcohol for 18h; Heating;
4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

tert-butyl alcohol
75-65-0

tert-butyl alcohol

4-Chloro-3-nitrobenzoic acid tert-butyl ester
157160-99-1

4-Chloro-3-nitrobenzoic acid tert-butyl ester

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 0 - 20℃; Inert atmosphere;94%
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 0 - 20℃; for 17h; Inert atmosphere;
2-amino-phenol
95-55-6

2-amino-phenol

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

2-(4-chloro-3-nitrophenyl)benzo[d]oxazole
32058-60-9

2-(4-chloro-3-nitrophenyl)benzo[d]oxazole

Conditions
ConditionsYield
With samarium(III) trifluoromethanesulfonate In ethanol; water at 80℃; for 3h;94%
2,2'-thiobis-ethanol
111-48-8

2,2'-thiobis-ethanol

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

3-amino-4-chloro-benzoic acid
2840-28-0

3-amino-4-chloro-benzoic acid

Conditions
ConditionsYield
In methanol; water92%
2,2-dimethoxyethylamine
22483-09-6

2,2-dimethoxyethylamine

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

4-[(2,2-dimethoxyethyl)amino]-3-nitrobenzoic acid

4-[(2,2-dimethoxyethyl)amino]-3-nitrobenzoic acid

Conditions
ConditionsYield
With triethylamine In dimethyl sulfoxide at 100℃; for 14h;92%
N-butylamine
109-73-9

N-butylamine

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

N-butyl-(4-chloro-3-nitrophenyl)carboxamide
59320-12-6

N-butyl-(4-chloro-3-nitrophenyl)carboxamide

Conditions
ConditionsYield
Stage #1: 4-chloro-3-nitrobenzoate With 1-hydroxy-pyrrolidine-2,5-dione; dicyclohexyl-carbodiimide In dichloromethane for 0.0833333h; ice bath;
Stage #2: N-butylamine In dichloromethane at 20℃; for 0.25h;
91%
4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

4-chloro-3-nitro-benzoyl chloride
38818-50-7

4-chloro-3-nitro-benzoyl chloride

Conditions
ConditionsYield
With thionyl chloride In dichloromethane; N,N-dimethyl-formamide Heating;90%
With thionyl chloride for 6h; Heating;84.7%
With phosphorus pentachloride at 140 - 150℃;
chloromethyl-(4-chloro-2-methyl-phenyl)-ether
83144-02-9

chloromethyl-(4-chloro-2-methyl-phenyl)-ether

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

4-Chloro-3-nitro-benzoic acid 4-chloro-2-methyl-phenoxymethyl ester
83144-00-7

4-Chloro-3-nitro-benzoic acid 4-chloro-2-methyl-phenoxymethyl ester

Conditions
ConditionsYield
With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate In dichloromethane for 0.25h; Heating;90%
toluene-4-sulfonamide
70-55-3

toluene-4-sulfonamide

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

N-(4-chloro-3-nitrophenyl)-4-methylbenzenesulfonamide
16330-01-1

N-(4-chloro-3-nitrophenyl)-4-methylbenzenesulfonamide

Conditions
ConditionsYield
With dipotassium peroxodisulfate; silver nitrate In toluene at 110℃; for 0.5h; Sealed tube;90%
4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

4-Chloro-3-nitrobenzoic acid tert-butyl ester
157160-99-1

4-Chloro-3-nitrobenzoic acid tert-butyl ester

Conditions
ConditionsYield
With thionyl chloride In tetrahydrofuran; 1,2-dichloro-ethane; N,N-dimethyl-formamide89%
59%
Multi-step reaction with 2 steps
1: SOCl2, DMF / 1,2-dichloro-ethane / 14 h / Heating
2: tetrahydrofuran / 0.5 h / 0 °C
View Scheme
Multi-step reaction with 2 steps
1: SOCl2 / dimethylformamide
View Scheme
Multi-step reaction with 2 steps
1: oxalyl dichloride / N,N-dimethyl-formamide; dichloromethane
2: pyridine
View Scheme
4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

A

1-cyclopropyl-1H-indole

1-cyclopropyl-1H-indole

B

4-Chloro-3-nitrobenzoic acid tert-butyl ester
157160-99-1

4-Chloro-3-nitrobenzoic acid tert-butyl ester

Conditions
ConditionsYield
With thionyl chloride In tetrahydrofuran; 1,2-dichloro-ethane; N,N-dimethyl-formamideA 89%
B n/a
1-(3-aminopropyl)-2-pyrrolidone
7663-77-6

1-(3-aminopropyl)-2-pyrrolidone

4-chloro-3-nitrobenzoate
96-99-1

4-chloro-3-nitrobenzoate

4-[N-(3′-aminopropyl)-2-pyrrolidone]-3-nitrobenzenesulfonic acid
312921-96-3

4-[N-(3′-aminopropyl)-2-pyrrolidone]-3-nitrobenzenesulfonic acid

Conditions
ConditionsYield
In dimethyl sulfoxide at 85℃; for 8h;89%

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