32097-05-5

Basic information

• Product Name: 2-Buten-1-one, 1-(4-methoxyphenyl)-3-methyl-
• CAS NO: 32097-05-5
• Molecular Formula: C12H14O2
• Molecular Weight: 190.242
• Mol File: 32097-05-5.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: 2-Buten-1-one, 1-(4-methoxyphenyl)-3-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Buten-1-one, 1-(4-methoxyphenyl)-3-methyl-(32097-05-5)
• EPA Substance Registry System: 2-Buten-1-one, 1-(4-methoxyphenyl)-3-methyl-(32097-05-5)

Safety Data

• Hazardous Substances Data: 32097-05-5(Hazardous Substances Data)

Upstream product

• 3350-78-5 3,3-Dimethylacryloyl chloride 
• 100-66-3 methoxybenzene 
• 37637-88-0 N-formamido-3-methyl-2-butenamide 
• 541-47-9 3-Methylbutenoic acid 
• 20912-79-2 4-methoxyphenacylidene dimethylsulphurane 
• 3900-79-6 toluene-4-sulfonic acid isopropylidenehydrazide 
• 369-57-3 benzenediazonium tetrafluoroborate 
• 456-27-9 4-nitrobenzenediazonium tetrafluoroborate 
• 84384-30-5 4-(4-methoxyphenyl)-2-methyl-3-butyn-2-ol 
• 115-19-5 2-methyl-but-3-yn-2-ol 
• 696-62-8 para-iodoanisole 
• 64-17-5 ethanol 
• 82938-20-3 3-methyl-1-(4-methoxyphenyl)-1-butanone 
• 55991-65-6 [1-(4-methoxyphenyl)vinyloxy]trimethylsilane 

Downstream Products

• 1168156-46-4 2-ethoxy-6-(4-methoxyphenyl)-4,4-dimethyl-3,4-dihydro-2H-pyran 
• 1616560-41-8 3-(4-methoxyphenyl)-5,5-dimethyl-1-phenyl-6-vinyl-1,4,5,6-tetrahydropyridazine 
• 1616560-22-5 1-(1-(4-methoxyphenyl)-3,3-dimethylhex-5-en-1-ylidene)-2-phenylhydrazine 
• 1616560-23-6 1-(1-(4-methoxyphenyl)-3,3-dimethylhex-5-en-1-ylidene)-2-phenylhydrazine 
• 1616560-09-8 1-(4-methoxyphenyl)-3,3-dimethylhex-5-en-1-one 
• 92236-80-1 N-tosyl-2-(α-hydroxybenzyl)-3,3-dimethylaziridine 
• 92236-78-7 (3,3-Dimethyl-aziridin-2-yl)-(4-methoxy-phenyl)-methanol 
• 70574-34-4 1-(4-methoxyphenyl)-5-methylcyclohexa-1,4-diene 
• 90-96-0 bis(p-methoxyphenyl)methanone 
• 74721-02-1 4'-methoxy-3,3-dimethylpent-4-enophenone 
• 74721-01-0 3-(4-Methoxy-phenyl)-5-methyl-hexa-1,4-dien-3-ol 
• 70574-33-3 (+/-)-1,3-(4-methoxyphenyl)-5-methyl-(1-methyl-2,5-dioxocyclopentyl)hexa-2,4-diene 

Relevant articles and documents

Alkene Synthesis by Photo-Wolff-Kischner Reaction of Sulfur Ylides and N-Tosylhydrazones

A visible-light-driven and room temperature photo-Wolff-Kischner reaction of sulfur ylides and N-tosylhydrazones has been developed for the first time to provide modular access to alkene synthesis. The high functional group tolerance and broad substrate scope were demonstrated by more than 60 examples. Both E- and Z-olefinic stereochemistry in the products could be controlled with excellent stereoselectivity. A series of mechanistic studies support that the reaction should proceed through a radical-carbanion crossover pathway, specifically involving addition of photo-generated sulfur ylide radical cations to N-tosylhydrazones to form carbanions and subsequent Wolff-Kischner process.

One-step synthesis of indanones through NbCl5-induced Friedel-Crafts reaction

Abstract This Letter describes the use of NbCl5 as the Lewis acid in Friedel-Crafts reactions, in which a bifunctional electrophile reacts inter- and intramolecularly with an aromatic ring to produce a number of indanones in a single step, main

p-Toluenesulfonic acid-promoted selective functionalization of unsymmetrical arylalkynes: a regioselective access to various arylketones and heterocycles

Regioselective hydration of a wide range of internal alkynes has been afforded in high to good yields by using PTSA in EtOH. The scope of the reaction of alkynes has been delineated. Arylaliphatic alkynes and diarylalkynes were regioselectively hydrated in good to excellent yields and short reaction times when the reaction was achieved under microwave irradiation. Moreover, diarylalkynes, arylenynes as well as diaryldiynes bearing a methoxy- or a thiomethyl substituent on the ortho position underwent a regioselective 5-endo-dig-cyclization to give a variety of 2-aryl- and 2-styrylbenzofuran or benzothiphene derivatives. We believe that, this new environmentally metal-free procedure combined to microwave irradiation would be in importance in the search of green laboratory-scale synthesis.