32136-85-9

Basic information

• Product Name: Benzene, [[(methylsulfonyl)methyl]sulfonyl]-
• CAS NO: 32136-85-9
• Molecular Formula: C8H10O4S2
• Molecular Weight: 234.297
• Mol File: 32136-85-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, [[(methylsulfonyl)methyl]sulfonyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [[(methylsulfonyl)methyl]sulfonyl]-(32136-85-9)
• EPA Substance Registry System: Benzene, [[(methylsulfonyl)methyl]sulfonyl]-(32136-85-9)

Safety Data

• Hazardous Substances Data: 32136-85-9(Hazardous Substances Data)

Upstream product

• 56772-75-9 {[(methylsulfanyl)methyl]sulfanyl}benzene 
• 59431-14-0 (methylsulfanyl)methyl phenyl sulfone 
• 1438396-95-2 (methylsulfinyl)methyl phenyl sulfone 
• 5000-44-2 1-phenylsulfonyl-2-propanone 
• 190672-15-2 ethyl (methylsulfanyl)phenylsulfonylacetate 
• 858835-74-2 1-benzenesulfonyl-1-methylsulfanyl-acetone 
• 108-98-5 thiophenol 
• 98-09-9 benzenesulfonyl chloride 
• 41480-11-9 2,4,6-tribromophenyl benzenesulfonate 
• 71804-83-6 Methanesulfonylmethylsulfanyl-benzene 
• 558-25-8 methyl fluorosulfonate 
• 591-51-5 phenyllithium 
• 7605-30-3 ethyl 2-phenylsulfonylacetate 
• 1125-25-3 S-methyl benzenethiosulfonate 

Downstream Products

• 82784-21-2 1-benzenesulfonyl-1-methanesulfonyl-ethane 
• 30904-40-6 3-nitrobenzenesulfonic acid anion 
• 104994-83-4 m-toluenesulfonate 
• 68743-27-1 3-Chloro-benzenesulfonic acid anion 
• 23566-08-7 benzenesulfonyl-bis-methanesulfonyl-methane 
• 138373-07-6 (1-Chloro-1-methanesulfonyl-ethanesulfonyl)-benzene 
• 3198-32-1 benzenesulfonate 
• 856060-76-9 benzenesulfonyl-(3,5-dichloro-phenylsulfanyl)-methanesulfonyl-methane 
• 856060-68-9 benzenesulfonyl-methanesulfonyl-p-tolylsulfanyl-methane 

Relevant articles and documents

On the thermal Pummerer rearrangement of substituted sulfoxides

Sulfoxides bearing thioester and ester groups at the position under heating at ca. 140C undergo Pummerer thermal rearrangement. However, for sulfonyl sulfoxide, a complex mixture of products is formed. Plausible mechanism is advanced(equation presented. 2013

Synthesis of novel 2-chloro-1,4-dihydropyridines by chlorination of 2-hydroxy-1,4-dihydropyridines with phosphorus oxychloride

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