32240-63-4

Basic information

• Product Name: cis-RuCl₂(CO)2(PPh₃)2
• CAS NO: 32240-63-4
• Molecular Weight: 752.579
• Mol File: 32240-63-4.mol
• Article Data: 28

Chemical Properties

• CAS DataBase Reference: cis-RuCl₂(CO)2(PPh₃)2(CAS DataBase Reference)
• NIST Chemistry Reference: cis-RuCl₂(CO)2(PPh₃)2(32240-63-4)
• EPA Substance Registry System: cis-RuCl₂(CO)2(PPh₃)2(32240-63-4)

Safety Data

• Hazardous Substances Data: 32240-63-4(Hazardous Substances Data)

Upstream product

• 15529-49-4 tris(triphenylphosphine)ruthenium(II) chloride 
• 118229-17-7 RuCl₂(P(C₆H₅)3)(C₅H₃N(CH₂CHCH₂)2) 
• 21264-30-2 dichloro bis(acetonitrile) palladium(II) 
• 77906-76-4 Ru(P(C₆H₅)3)2(CO)2(NO₂)(ONO) 
• 77906-76-4 Ru(P(C₆H₅)3)2(CO)2(ONO)2 
• 20332-49-4 tricarbonylbis(triphenylphosphine)ruthenium⁽⁰⁾ 
• 2696-92-6 nitrosylchloride 
• 157072-60-1 (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) 
• 6316-86-5 trityl thionitrite 
• 14741-36-7 [Ru(CO)3(triphenylphosphine)2] 
• 134290-01-0 {Ru(η2-C(CCC6H5)CHC6H5)(CO)2(P(C6H5)3)2} 
• 16594-36-8 {RuCl(CO)3((C₆H₅)3P)2}⁽¹⁺⁾*{AlCl₄}^(1-)={RuCl(CO)3(C₁₈H₁₅P)2}{AlCl₄} 
• 124-41-4 sodium methylate 
• 201230-82-2 carbon monoxide 

Downstream Products

• 105811-82-3 dicarbonylbis(trifluoromethanesulphonato)bis(triphenylphosphine)ruthenium(II) 
• 118774-03-1 {Ru(CO)(Cl)(1,10-phenanthroline)(PPh₃)2}PF₆ 
• 14564-35-3 cis-dicarbonyldichlorobis(triphenylphosphine)ruthenium(II) 
• 118774-00-8 {Ru(CO)(Cl)(1,10-phenanthroline)(PPh₃)2}Cl 
• 107478-77-3 {Ru(CO)H(1,10-phenanthroline)(PPh₃)2}Cl 
• 20332-49-4 tricarbonylbis(triphenylphosphine)ruthenium⁽⁰⁾ 
• 35880-54-7 {ruthenium⁽⁰⁾ dicarbonyltris(triphenylphosphine)} 
• 99597-27-0 RuCl(CO)(C₅H₄NO)(P(C₆H₅)3)2 
• 16594-36-8 {RuCl(CO)3((C₆H₅)3P)2}⁽¹⁺⁾*{AlCl₄}^(1-)={RuCl(CO)3(C₁₈H₁₅P)2}{AlCl₄} 
• 14741-36-7 [Ru(CO)3(triphenylphosphine)2] 
• 14564-35-3 all-trans-[RuCl₂(CO)2(PPh₃)2] 
• 136050-11-8 {(triphenylphosphine)(carbonyl)2ruthenium(μ2-ethanethiolato)(μ3-ethanethiolato)sodium(THF)}2 
• 136050-16-3 cis,cis,trans-Cl((Et)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II) 
• 136050-00-5 cis,cis,trans-bis(ethanethiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II) 

Relevant articles and documents

Selenolatovinylidene complexes: Metal-mediated alkynyl selenoether rearrangements

The reactions of [RuCl2(PPh3)3] and [RuCl-(PPh3)2(η-C5H5)] with PhC≡CSeiPr provide the selenolatovinylidene complexes [RuCl2{=C=C(SeiPr)Ph}(PPhs

Reactions of [Ru(CO)2(PPh3)3] with alkynylphosphonium salts: A phosphinoallene complex

[Ru(CO)2(PPh3)3] reacts with either HC=CCH2Br or [HC=CCH2SMe2]Br to provide the σ-allenyl complex [Ru(CH=C=CH2)Br(CO)2(PPh 3)2]; however, with [HC=CCH2PPh3]Br, the salt [Ru(γ2-H2C=C=CHPPh3)(CO) 2(PPh3)2]Br is obtained, which may be described as a complex of a phosphonioallene on the basis of crystallographic data for [Ru(γ2-H2C=C=CHPPh3)(CO) 2(PPh3)2]2Br(PF6) and a comparison of spectroscopic data with those for the simple allene complex [Ru(γ2-H2C=C=CH2)(CO) 2(PPh3)2].

Synthesis, characterization, reactivity and theoretical studies of ruthenium carbonyl complexes containing ortho-substituted triphenyl phosphanes

A series of ruthenium o-phosphane complexes was synthesized and characterized. The reactivity of the prepared complexes was studied by using them as catalysts for the hydroformylation of 1-hexene. The activities depended on the binding mode of the phosphane and on the strength of the ruthenium-phosphane interaction. Strongly coordinated chelating [2-(dimethylamino)phenyl]-(diphenyl) phosphane and [2-(methylthio)phenyl]- (diphenyl) phosphane showed poor activity, while weakly chelated [2-(methoxy)phenyl]-(diphenyl) phosphane and non-chelating phosphanes such as [2-(methyl)phenyl]-(diphenyl) phosphane or [2-(ethyl)phenyl]-(diphenyl) phosphane led to higher activities.