3246-27-3

Usage

Synthesis Reference(s)

Synthetic Communications, 20, p. 2033, 1990 DOI: 10.1080/00397919008053134

InChI:InChI=1/C8H14O2/c1-5-6-7(9)10-8(2,3)4/h5-6H,1-4H3/b6-5+

Upstream product

• 41108-81-0 tert-butyl (trimethylsilyl)acetate 
• 75-07-0 acetaldehyde 
• 70030-50-1 but-2-enethioic acid S-phenyl ester 
• 75-65-0 tert-butyl alcohol 
• 3068-88-0 4-methyloxetan-2-one 
• 865-47-4 potassium tert-butylate 
• 74-88-4 methyl iodide 
• 10487-71-5 crotonyl chloride 
• 86302-43-4 (tert-Butoxycarbonylmethylene)triphenylphosphorane 
• 218457-99-9 tert-butyl but-2-ynoate 
• 3724-65-0 2-butenoic acid 
• 115-11-7 isobutene 

Downstream Products

• 30434-65-2 3,4,4-trimethylcyclopent-2-en-1-one 
• 5707-59-5 2-benzyl-crotonic acid 
• 93877-17-9 2,2-dibenzyl-3-butenoic acid 
• 77256-03-2 t-butyl 3-methyl-4-oxo-4-(2-isopropyl-3,4-dimethoxyphenyl)butyrate 
• 106-98-9 1-butylene 
• 2308-38-5 tert-butyl butyrate 
• 75567-10-1 1-tert-Butoxy-2-butanol 
• 50745-65-8 bromo-4 butene-2 oate de t-butyle 
• 214261-09-3 (2R,3R,3aR,4R,4aR,5S,8R,8aS,5'S,7E)-2-(10'-(1,1)-dimethylethyloxycarbonyl-5',7',9'-trimethyl-7',9'-decadien-1'-yl)-3-[(1,1,1-triphenyl)methoxymethyl]-5,10,10-trimethyl-5,8-methanooctahydro-2H-isoxazolo[3,2-b]benzoxazole 
• 161010-97-5 tert-butyl (3S,αS)-3-[N-benzyl-N-(α-methylbenzyl)amino]butanoate 

Relevant academic research and scientific papers

Kinetic resolution of 1,2-diols through highly site- and enantioselective catalytic silylation

(Chemical Equation Presented) Resolved to silylate: A chiral silylation catalyst is used for kinetic resolution of three classes of acyclic 1,2-diols. The catalyst differentiates, with excellent precision, between the two hydroxy groups of a substrate. The majority of the diols, obtained in high enantiomeric purity, cannot be accessed with similar stereochemical purity through catalytic asymmetric dihydroxylation.

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