32476-02-1Relevant academic research and scientific papers
Palladium-Catalyzed Carbonylative Homocoupling of Aryl Iodides for the Synthesis of Symmetrical Diaryl Ketones with Formic Acid
Wu, Fu-Peng,Peng, Jin-Bao,Qi, Xinxin,Wu, Xiao-Feng
, p. 173 - 177 (2018)
A convenient method for the palladium-catalyzed carbonylative homocoupling of aryl iodides was developed. With formic acid as the CO source, various symmetrical diaryl ketones were synthesized in moderate to good yield in the presence of a palladium catalyst.
Palladium imine-pyridine-imine complex immobilized on graphene oxide as a recyclable catalyst for the carbonylative homo-coupling of aryl halides
Niakan, Mahsa,Asadi, Zahra,Khosrozadeh, Fatemeh
, p. 850 - 863 (2020/12/18)
A heterogeneous 3-N,N,N-(II) Pd(OAc)2 catalyst was prepared from the reaction of Pd(OAc)2 with Si-Prn-N = C-Py-C = N-Prn-Si immobilized on graphene oxide (GO-Si-Prn-N = C-Py-C = N-Prn-Si-GO). The prepared catalyst was characterized by inductively coupled plasma optical emission spectroscopy, Fourier transform infrared (FT-IR) spectroscopy, Raman spectroscopy, energy dispersive X-ray spectroscopy, X-ray diffraction, UV-vis spectroscopy, BET surface area, scanning electron microscopy, transmission electron microscopy, and thermogravimetric analysis. The catalyst was employed as a heterogeneous catalyst for carbonylative homo-coupling of aryl iodides and bromides under carbon monoxide gas-free condition. Cr(CO)6 was used as the carbon monoxide source and the desired symmetrical diaryl ketones were achieved in good to excellent yields. Moreover, the catalyst was reused up to five consecutive cycles without significant loss of activity.
Ultrafast Chemistry: Cobalt Carbonyl-Mediated Synthesis of Diaryl Ketones under Microwave Irradiation
Enquist, Per-Anders,Nilsson, Peter,Larhed, Mats
, p. 4875 - 4878 (2007/10/03)
(Equation Presented) By combining the advantages of metal activation, in situ carbon monoxide delivery, and microwave heating, benzophenones were efficiently synthesized in 6-10 s. These ultrafast carbonylation reactions occur under air by flash heating o
The 'Inverse Electron-demand' Diels-Ader Reaction in Polymer Synthesis. Part 1. A Convenient Synthetic Route to Diethynyl Aromatic Compounds
Royles, Brodyck J. L.,Smith, David M.
, p. 355 - 358 (2007/10/02)
The simple procedure whereby acetophenone derivatives are converted, by reaction with phosphoryl chloride and N,N-dimethylformamide, into β-chlorocinnamaldehydes, and thence, by base-induced elimination, into ethynylarenes, has been extended to diketones of the type MeCOC6H4COMe (m- and p-) and (p-MeCOC6H4)2X (X = O, S, SO2, CH2, CO, or a single bond): the corresponding diethynyl compounds are obtained by this route in acceptable yield. 1,3,5-Triacetylbenzene is similarly converted into 1,3,5-triethynylbenzene.
