325465-26-7Relevant academic research and scientific papers
Synthesis and structure of a monomeric aluminum(i) compound [{HC(CMeNAr)2}Al] (AR = 2,6-iPr2C6H3): A stable aluminum analogue of a carbene
Cui, Chunming,Roesky, Herbert W.,Schmidt, Hans-Georg,Noltemeyer, Mathias,Hao, Haijun,Cimpoesu, Fanica
, p. 4274 - 4276 (2007/10/03)
A monovalent aluminum monomer [{HC(CMeNAr)2}Al] was obtained by reduction of the corresponding aluminum(III) diiodide. The molecular structure shows a unique two-coordinate aluminum center and a planar heterocyclic Al-N-C-C-C-N six-membered ring system (see picture).A nonbonded lone pair of electrons on the Al atom indicates the Lewis base character of the aluminum center. Ar = 2,6-iPr2C6H3.
