32579-95-6

Basic information

• Product Name: 1,2-O-isopropylidene-3-O-methyl-6-O-(p-toluenesulfonyl)-α-D-glucofuranose
• Synonyms: 1,2-O-isopropylidene-3-O-methyl-6-O-(p-toluenesulfonyl)-α-D-glucofuranose
• CAS NO: 32579-95-6
• Molecular Weight: 388.439
• Mol File: 32579-95-6.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1,2-O-isopropylidene-3-O-methyl-6-O-(p-toluenesulfonyl)-α-D-glucofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-O-isopropylidene-3-O-methyl-6-O-(p-toluenesulfonyl)-α-D-glucofuranose(32579-95-6)
• EPA Substance Registry System: 1,2-O-isopropylidene-3-O-methyl-6-O-(p-toluenesulfonyl)-α-D-glucofuranose(32579-95-6)

Safety Data

• Hazardous Substances Data: 32579-95-6(Hazardous Substances Data)

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 43138-65-4 1,2-O-isopropylidene-3-O-methyl-α-D-glucofuranose 
• 50-99-7 D-glucose 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 68244-21-3 5-O-carbamoyl-6-chloro-6-deoxy-1,2-O-isopropylidene-3-O-methyl-α-D-glucofuranose 
• 43138-64-3 1,2-:5,6-di-O-isopropylidene-3-O-methyl-α-D-glucofuranose 

Downstream Products

• 511269-81-1 1,2-O-isopropylidene-3-O-methyl-6-O-tosyl-5-O-trifluoromethanesulfonyl-α-D-glucofuranose 
• 511269-83-3 Toluene-4-sulfonic acid (S)-2-azido-2-((3aR,5R,6S,6aR)-6-methoxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethyl ester 

Relevant articles and documents

Catalytic enantioselective reactions. Part 7. Synthesis of new β-aminoalcohols derived from α-D-glucose as chiral catalysts for the catalytic enantioselective addition of diethylzinc to aldehydes

A series of new 1,2-O-isopropylidene-3-O-methyl-6-deoxy-6-N,N-dialkylamino-α-D-glucof uranoses 1 and 1,2-O-isopropylidene-3,6-dideoxy-6-N,N-dialkylamino-α-D-glucofuranose s 1' were prepared from α-D-glucose and their enantioselectivities compared as chiral catalysts for the ethylation of benzaldehyde and heptanal with diethylzinc.

Control of regioselectivity in reactions of dialkylstannylene acetals. Part I. A dramatic reversal of regioselectivity in mono-p-toluenesulfonation reactions

The regioselectivities of p-toluenesulfonation reactions of dialkylstannylene acetals obtained from a number of carbohydrate-derived terminal 1,2-diols in the absence of added nucleophiles have been explored as functions of the carbohydrate structure, the

Inversion of regioselectivity in reactions of diols through the use of hexamethylenestannylene acetals as intermediates

Hexamethylenestannylene acetals obtained from a variety of carbohydrate-derived terminal 1,2-diols give good to excellent regioselectivity for tosylation at the secondary oxygen. In contrast, non-cyclic dialkylstannylene acetals react mainly at the primary oxygen. These results are attributed to the greater stability of the dominant stannylene acetal dimers for hexamethylenestannylene acetals.