3297-75-4Relevant academic research and scientific papers
Titanocene(III)-catalyzed conversion of N-(epoxyalkyl)anilines into indolines
MacIejewski, John P.,Wipf, Peter
, p. 92 - 119 (2011/06/20)
Densely substituted indolines and azaindolines can be obtained by the titanocene(III) chloride catalyzed reductive opening of N-(oxiran-2-ylmethyl) anilines. The reaction optimization, substrate scope, and limitations are discussed, and a mechanistic pathway for the epoxideopening rearrangement is proposed. ARKAT-USA, Inc.
Copper(II)-catalyzed aminooxygenation and carboamination of N-aryl-2-allylanilines
Sherman, Eric S.,Chemler, Sherry R.
supporting information; experimental part, p. 467 - 471 (2009/11/30)
The scope of the intramolecular copper(II)-catalyzed carboamination and aminooxygenation reactions of olefins has been extended to include N-aryl-2-allylanilines. These substrates exhibit divergent reactivity under catalytic vs. stoichiometric conditions.
Titanocene(III)-catalyzed formation of indolines and azaindolines
Wipf, Peter,Maciejewski, John P.
supporting information; experimental part, p. 4383 - 4386 (2009/05/30)
(Chemical Equation Presented) Reductive cyclization of epoxides tethered to substituted anilines and aminopyridines in the presence of 3 mol % of titanocene dichloride and stoichiometric manganese metal promotes a radical annulation to form 3,3-disubstituted indolines and azaindolines.
Synthesis and thermal reactions of N-(2,3-epoxypropyl)diphenylamine
Barvainiene,Stanisauskaite,Getautis
, p. 718 - 721 (2008/03/11)
The synthesis of N-(2,3-epoxypropyl)diphenylamine is reported. It was found that thermal opening of the oxirane ring of N-(2,3-epoxypropyl)diphenylamine occurred both at the secondary and the tertiary carbon atoms but the basic reaction product is 3-hydro
Hydrazones possessing a phenyl-1,2,3,4-tetrahydroquinoline moiety as hole transporting materials
Getautis, Vytautas,Stanisauskaite, Albina,Malinauskas, Tadas,Stumbraite, Jolanta,Gaidelis, Valentas,Jankauskas, Vygintas
, p. 1401 - 1409 (2007/10/03)
Hydrazones containing 1-phenyl-1,2,3,4-tetrahydroquinoline units were synthesized starting from diphenylamine. These compounds were found to constitute novel hole transporting materials and were characterized by the time of flight method. The hole drift m
