34692-10-9Relevant articles and documents
Reactions of 'GaI' with organometallic transition metal halides
Coombs, Natalie D.,Stasch, Andreas,Aldridge, Simon
, p. 449 - 456 (2008)
Two approaches towards the synthesis of phosphine ligated half-sandwich complexes [(ηx-CxHx)M(PR3)2GaI2]n containing diiodogallyl ligands have been investigated. Insertion of 'GaI' into the Mo-I bond of (η7-C7H7)Mo(CO)2I has been shown to yield the crystallographically characterized dimeric complex [(η7-C7H7)Mo(CO)2GaI2]2 (2). Attempts to substitute the carbonyl ligands by the phosphine ligand dppe [dppe = bis(diphenylphosphino)ethane] have been shown instead to yield the sparingly soluble complex [(η7-C7H7)Mo(CO)2GaI2]2(μ-dppe) (3) in which the phosphine bridges two [(η7-C7H7)Mo(CO)2GaI2] units via a pair of P → Ga donor/acceptor bonds. By contrast, attempts to insert 'GaI' directly into the metal-halogen bond of phosphine ligated complexes such as (η5-C5H5)Ru(PPh3)2Cl or (η5-C5H5)Ru(dppe)Cl have been shown to result in the formation of the tetraiodogallate species(η5-C5H5)Ru(PPh3)2(μ-I)GaI3 (5) and [(η5-C5H5)Ru(dppe)]+[GaI4]- (7).
Acid-promoted sp3 C-H bond cleavage in a series of (2-allylphenoxo) ruthenium(II) complexes. Mechanistic insight into the aryloxo-acid interaction and bond cleavage reaction
Hirano, Masafumi,Murakami, Masahiro,Kuga, Toshinori,Komine, Nobuyuki,Komiya, Sanshiro
, p. 381 - 393 (2012/05/07)
A series of RuCp[OC6H3(CH2CH=CH 2-2)(R)](PPh3)n complexes (n = 2, R = H (1a); n = 1, R = 4-OMe (2b), 4-Me (2c), 4-Ph (2d), 4-Br (2e), 4-NO2 (2f), 6-OMe (2g), 6-Me (2h), 6-Ph (2i)) have been
Reactions of ruthenium cyclopropenyl complexes with trimethylsilyl azide
Chang,Lin,Liu,Wang
, p. 3154 - 3159 (2007/10/03)
Treatment of the phenyl substituted cyclopropenyl complex [Ru]-C=C(Ph)CHPh (1a, [Ru]= (η5-C5H5)(PPh3) 2Ru) with Me3SiN3 in THF in the presence of NH4PF6 at
