33240-72-1Relevant academic research and scientific papers
Chemistry, kinetics, and spectroscopy of highly hindered diarylcarbenes. The case of decachlorodiphenylcarbene
Tomioka, Hideo,Hirai, Katsuyuki,Nakayama, Takehito
, p. 1285 - 1289 (2007/10/02)
Bis(pentachlorophenyl)diazomethane (1a) was prepared, and reactivities of perchlorodiphenylcarbene (2a) generated by photolysis of la were investigated not only in terms of product analysis but also by using flash photolysis techniques. Although the major
Synthesis of the Sterically Hindered Bis(pentachlorophenyl)acetic Acid and Derived Stable Free Radicals
O'Neill, Pat,Hegarty, Anthony F.
, p. 4421 - 4426 (2007/10/02)
Bis(pentachlorophenyl)acetic acid esters were synthesized from the α-hydroxydiaryl acetate esters 13 via the free radicals 15 formed on homolytic cleavage of the α-chloro compounds 14.The acid 8 underwent rapid decarboxylation in basic solution (e.g., Et3
Extensive Chlorination of Methylnaphthalenes, Friedel-Crafts Alkylation of Pentachlorobenzene by Heptachloro(chloromethyl)naphthalenes, and Related Results
Garcia, R.,Riera, J.,Carilla, J.,Julia, L.,Molins, E.,Miravitlles, C.
, p. 5712 - 5719 (2007/10/02)
The chlorination of 2-methylnaphthalene (1) and 1-methylnaphthalene (12) by means of Silberrad's reagent (initial components: SO2Cl2, S2Cl2, and AlCl3) has been performed.From 1 or 12, the following compounds have been synthesized for first time: nonachlo
