33288-22-1Relevant academic research and scientific papers
The organocatalytic synthesis of perfluorophenylsulfides: Via the thiolation of trimethyl(perfluorophenyl)silanes and thiosulfonates
Cai, Zhihua,Du, Guangfen,He, Lin,Lin, Muze,Luo, Jinyun,Wu, Leifang
supporting information, p. 9237 - 9241 (2021/11/13)
The organic superbase t-Bu-P4-catalyzed direct thiolation of trimethyl(perfluorophenyl)silanes and thiosulfonates was developed. Yields of perfluorophenylsulfides of up to 97% under catalysis of 5 mol% t-Bu-P4 were achieved. This method was shown to provide an efficient way to construct the perfluorophenyl-sulfur bond under mild metal-free reaction conditions. This journal is
Synthesis of polyfluoroarylalkyl sulfide compounds
Ward, Wayne E.,Sicree, Stephen,Chen, Brian,Tamborski, Christ
, p. 73 - 78 (2007/10/02)
Syntheses of RC6F4SR' compounds (where R = F, C6H5, H, R' = alkyl, trifluorovinyl) have been accomplished through reaction between ArfSM (where M = Cu, MgX) and an alkyl or trifluorovinyl halide in dimethylacetamide solvent.Minor by-products from competing reactions have been partially characterized by GC-MS analysis. - Keywords: Synthesis; Polyfluoroalkyl sulfides; NMR spectroscopy; Mass spectrometry
