3342-69-6Relevant articles and documents
ORGANOTIN BIOCIDES. V. THE STRUCTURE OF DICYCLOHEXYLTIN DICHLORIDE
Molloy, K. C.,Quill, K.,Nowell, I. W.
, p. 271 - 280 (1985)
The crystal and molecular structure of dicyclohexyltin dichloride has been solved by heavy atom methods in conjunction with least-squares data collected on a two-circle automatic diffractometer.Crystals are orthorhombic, space group Pbcm, cell dimensions a 6.671(5), b 9.445(6), c 24.203(12) Angstroem, U 1525.0 Angstroem3 and Z=4.The structure was refined using 1527 reflections to final discrepancy factors of R=0.047 and R'=0.058.The local geometry at tin is a severely distorted trans-R2SnCl4 octahedron.Chlorine atoms serve as bridging groups to link sub-units into a one dimensional polymer along b.
Electrophilic cleavage of tin-alicyclic and tin-aryl bonds involving the synthesis of cyclohexyl-tin, -tellurium and -antimony compounds - Part I
Singhal, Kiran
, p. 542 - 544 (2007/10/02)
Cyclohexyl-tin, -tellurium and -antimony halides have been obtained in good yields by the electrophilic cleavage of Sn-C bond(s) from symmetrical and unsymmetrical cyclohexyl tins, CynPnPh4-n (n = 1, 2, 4) employing Br2, I2, ICl, IBr, TeCl4 and SbCl5 in CCl4 under mild conditions.