3344-45-4Relevant academic research and scientific papers
Regioselective synthesis of substituted 1-indanols, 2,3-dihydrobenzofurans and 2,3-dihydroindoles by electrochemical radical cyclization using an arene mediator
Kurono, Nobuhito,Honda, Eiichi,Komatsu, Fumikazu,Orito, Kazuhiko,Tokuda, Masao
, p. 1791 - 1801 (2007/10/03)
Electrochemical reduction of haloarenes carrying 2-(1-hydroxybut-3-enyl), 2-allyloxy or N-allyl-N-methylamino group in the presence of phenanthrene as a mediator generated the corresponding aryl radicals and gave the corresponding 5-exo cyclization produc
Regioselective Radical Cyclization by Electrochemical Reduction Using an Arene Mediator. Environmentally Benign Method
Kurono, Nobuhito,Honda, Eiichi,Komatsu, Fumikazu,Orito, Kazuhiko,Tokuda, Masao
, p. 720 - 721 (2007/10/03)
Electrochemical reduction of 2-(but-3-enyl)-1-haloarenes in the presence of phenanthrene as a mediator generated the corresponding aryl radicals and gave cyclized products in good yields. Higher regio- and stereoselectivities than those of usual radical cyclization using AIBN-TBTH were achieved.
Directed ortho metalation reactions. Convergent synthesis of "angular" anthracyclinones ochromycinone and X-14881 C
Katsuura, K.,Snieckus, V.
, p. 124 - 130 (2007/10/02)
Convergent syntheses of the benzanthraquinone natural products X-14881 C (2c) and ochromycinone (2d) have been achieved using aromatic directed metalation strategies.Key steps involve (a) the condensations of dilithiated cis-tetralol (13a) with the ald
DIRECTED ORTHO METALATION REACTIONS. SYNTHESIS OF NATURALLY-OCCURRING BENZANTHRAQUINONES X-14881 C AND OCHROMYCINONE
Katsuura, K.,Snieckus, V.
, p. 9 - 12 (2007/10/02)
The synthesis of the benzanthraquinone natural products X-14881 C (1c) and ochromycinone (1a) via an aromatic directed metalation strategy (Scheme 1) is described.
SYNTHESE DU METHOXYCARBONYL-3 INDENE ET DE METHOXYCARBONYL-4 DIHYDRO-1,2 NAPHTALENES. OBTENTION DES β-TETRALONES A PARTIR DES α-TETRALONES CORRESPONDANTES
Vebrel, Joel,Carrie, Robert
, p. 161 - 166 (2007/10/02)
The synthesis of variously substituted 3-methoxycarbonylindene and 4-methoxycarbonyl-1,2-dihydronaphthalenes is described.A simple and efficient method for the transformation of 1-tetralone into 2-tetralone is reported.
