96239-80-4

Upstream product

• 5425-44-5 2-Phenyl-[1,3]dithiane 
• 14944-23-1 3-methyl-1-tetralone 
• 22436-06-2 2-methyl-3-phenylpropanol 
• 72277-22-6 3-Methyl-4-phenyl-butansaeure-ethylester 
• 83303-64-4 3-Methyl-4-phenylbutanenitrile 
• 3344-45-4 cis-3-methyl-1-tetralol 
• 111539-81-2 ethyl 3-methyl-4-(1,3-dithiopropano)-4-phenylbutyrate 
• 111539-90-3 N,N-Diethyl-2-[hydroxy-((6R,8R)-8-hydroxy-6-methyl-5,6,7,8-tetrahydro-naphthalen-1-yl)-methyl]-6-methoxy-benzamide 
• 111539-83-4 Toluene-4-sulfonic acid 2-methyl-3-phenyl-propyl ester 
• 70946-17-7 N,N-diethyl-2-formyl-6-methoxybenzamide 
• 51674-10-3 N,N-diethyl-2-methoxybenzamide 
• 111539-93-6 3-methyl-8-formyl-cis-1-tetralol 

Downstream Products

• 111540-00-2 ochromycinone 
• 111539-99-2 8-Methoxy-3-methyl-2-phenylselanyl-3,4-dihydro-2H-benzo[a]anthracene-1,7,12-trione 
• 96239-81-5 (1S,2S)-1-Hydroxy-8-methoxy-3-methyl-2-phenylselanyl-1,2,3,4-tetrahydro-benzo[a]anthracene-7,12-dione 
• 96239-81-5 (1S,2S)-1-Hydroxy-8-methoxy-3-methyl-2-phenylselanyl-1,2,3,4-tetrahydro-benzo[a]anthracene-7,12-dione 

Relevant academic research and scientific papers

Directed ortho metalation reactions. Convergent synthesis of "angular" anthracyclinones ochromycinone and X-14881 C

Convergent syntheses of the benzanthraquinone natural products X-14881 C (2c) and ochromycinone (2d) have been achieved using aromatic directed metalation strategies.Key steps involve (a) the condensations of dilithiated cis-tetralol (13a) with the ald

DIRECTED ORTHO METALATION REACTIONS. SYNTHESIS OF NATURALLY-OCCURRING BENZANTHRAQUINONES X-14881 C AND OCHROMYCINONE

The synthesis of the benzanthraquinone natural products X-14881 C (1c) and ochromycinone (1a) via an aromatic directed metalation strategy (Scheme 1) is described.