14944-23-1Relevant articles and documents
Lewis Acid Promoted Dearomatization of Naphthols
Boldrini, Cosimo,Casti?eira Reis, Marta,Harutyunyan, Syuzanna R.,Kulish, Kirill,Pérez, Juana M.
, p. 15843 - 15846 (2020)
Two-step dearomative functionalization of naphthols promoted by Lewis acids and copper(I) catalysis was developed. Initially, Lewis acid complexation inverted the electronic properties of the ring and established an equilibrium with the dearomatized counterpart. Subsequent trapping of the dearomatized intermediate with organometallics as well as organophosphines was demonstrated and provided the corresponding dearomatized products.
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Bachmann,Struve
, p. 1618 (1940)
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Cooperative catalysis approach to intramolecular hydroacylation
Beletskiy, Evgeny V.,Sudheer,Douglas, Christopher J.
experimental part, p. 5884 - 5893 (2012/09/21)
Prior examples of hydroacylation to form six- and seven-membered ring ketones require either embedded chelating groups or other substrate design strategies to circumvent competitive aldehyde decarbonylation. A cooperative catalysis strategy enabled intram