334757-47-0Relevant academic research and scientific papers
The configurational stability of an enantioenriched α-thiobenzyllithium derivative and the stereochemical course of its electrophilic substitution reactions; synthesis of enantiomerically pure, tertiary benzylic thiols
Stratmann, Oliver,Kaiser, Bernd,Frohlich, Roland,Meyer, Oliver,Hoppe, Dieter
, p. 423 - 435 (2007/10/03)
The lithium compound (S)-7, formed by deprotonation of the (S)-S-1-phenylethyl thiocarbamate (S)-10, is configurationally stable at -70°C. Even at elevated temperatures it racemizes only very slowly. It represents the first essentially enantiopure αthioca
