336-15-2

Usage

Uses

Used in Industrial Processes:
CHLOROPERFLUOROCYCLOHEXANE is used as a solvent in various industrial applications, including the production of plastics, electronics, and pharmaceuticals. Its high chemical stability and resistance to environmental factors make it a valuable component in these industries.
Used in Manufacturing:
In the manufacturing sector, CHLOROPERFLUOROCYCLOHEXANE is utilized as a solvent to facilitate the production of various products. Its properties allow for efficient manufacturing processes and the creation of high-quality end products.
Regulation and Environmental Considerations:
Due to its status as a persistent organic pollutant and its potential negative impacts on human health and the environment, the use and emission of CHLOROPERFLUOROCYCLOHEXANE are regulated in many countries. This aims to minimize its harmful effects and promote safer alternatives in industrial applications.

InChI:InChI=1/C6ClF11/c7-1(8)2(9,10)4(13,14)6(17,18)5(15,16)3(1,11)12

Upstream product

• 558-64-5 docosafluoro-bicyclohexyl 
• 108-90-7 chlorobenzene 
• 95-50-1 1,2-dichloro-benzene 
• 830-23-9 2,3,3,4,5,6,6-heptafluoro-1-chloro-cyclohexa-1,4-diene 
• 15145-21-8 1-chloro-2,3,3,4,4,5,5,6,6-nonafluorocyclohexene 
• 7782-50-5 chlorine 

Downstream Products

• 308-24-7 undecafluorocyclohexane 
• 336-12-9 1,2-dibromo-decafluoro-cyclohexane 
• 336-14-1 1,2-dichlorodecafluorocyclohexane 
• 355-75-9 decafluorocyclohex-1-ene 

Relevant academic research and scientific papers

FLUORINATION OF POLYHALOGENATED UNSATURATED COMPOUNDS WITH VANADIUM PENTAFLUORIDE

Vanadium pentafluoride reacts with polyfluorinated and polychlorinated olefins, alkadienes, cycloalkenes and cyclodienes in CFCl3 or without a solvent at -25 deg C to 100 deg C, forming products of addition of two fluorine atoms across the C=C bond.

ACTION OF VANADIUM AND ANTIMONY PENTAFLUORIDES ON POLYFLUORINATED DERIVATIVES OF CYCLOHEXADIENE

Polyfluorinated 1,3- and 1,4-cyclohexadienes are fluorinated by vanadium fluoride at -25 to 25 deg C.The olefinic fragments of perfluoro-1,3- and perfluoro-1,4-cyclohexadienes are close to each other in reactivity.Under the influence of vanadium pentafluoride the fluorine atoms add to 1-R-heptafluoro-1,4-cyclohexadienes preferentially at the multiple bond containing the less electron-withdrawing substituent.At -80 to 20 deg C antimony pentafluoride leads to isomerization of the polyfluorinated derivatives of cyclohexadiene.

REACTION OF POLYFLUORINATED CYCLOALKANES WITH VANADIUM, ANTIMONY, AND NIOBIUM PENTAFLUORIDES

Polyfluorinated cycloalkanes are fluorinated by vanadium pentafluoride at 25-60 deg C.Conjugation between the C=C bond of the cycloalkene and the aromatic ring facilitates the reaction, whereas the reactivity of the unconjugated olefin fragment is lower than or is equal to that of the aromatic ring.The antimony pentafluoride fluorinates polyhalogenocyclohexenes at 150 deg C, while niobium pentafluoride does not exhibit fluorinating characteristics under these conditions.