33722-96-2Relevant academic research and scientific papers
Aryl Ether Syntheses via Aromatic Substitution Proceeding under Mild Conditions
Ando, Shin,Tsuzaki, Marina,Ishizuka, Tadao
, p. 11181 - 11189 (2020)
In this study, mild conditions for aromatic substitutions during the syntheses of aryl ethers were developed. In the reaction conditions, the choices of solvent, base, and the sequence for the addition of the reagents proved important. A wide variety of alcohols were used directly as nucleophiles and smoothly reacted with aryl chlorides that possessed either a nitro or a cyano group at either the ortho- or para-position. Controlled experiments we performed suggested that the reaction underwent a charge-transfer process mediated by a combination of DMF and tert-BuOK.
Metal-free synthesis of aryl ethers in water
Lindstedt, Erik,Ghosh, Raju,Olofsson, Berit
supporting information, p. 6070 - 6073 (2014/01/06)
The first arylation of allylic and benzylic alcohols with diaryliodonium salts is reported. The reaction yields alkyl aryl ethers under mild and metal-free conditions. Phenols are arylated to diaryl ethers in good to excellent yields. The reaction employs diaryliodonium salts and sodium hydroxide in water at low temperature, and excess amounts of the coupling partners are avoided.
Synthesis of Aryl Azide Analogues of Insect Juvenile Hormones as Reagents for the Photoaffinity Labeling of Juvenile Hormone Binding Proteins
Stupp, Hans-Peter,Peter, Martin G.
, p. 327 - 331 (2007/10/02)
The azidophenyl 6,7-epoxygeranyl ethers rac-4c and rac-4d and the azidobenzoate rac-6 were synthesized. p-Azidophenyl 6,7-epoxygeranyl ether (rac-4c) shows a high affinity to the juvenile hormone binding protein of the migratory locust, Locusta migratoria
Phenyl ethers having juvenile hormone activity
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, (2008/06/13)
Novel nitrophenyl and halophenyl compounds having a side chain substituted with hydroxy or ether radical useful for insect control.
