905718-45-8

Basic information

• Product Name: (4-Nitrophenyl)phenyliodonium trifluoromethanesulfonate
• Synonyms: (4-Nitrophenyl)phenyliodonium trifluoromethanesulfonate
• CAS NO: 905718-45-8
• Molecular Formula: CF₃O₃S*C₁₂H₉INO₂
• Molecular Weight: 475.1789396
• Mol File: 905718-45-8.mol
• Article Data: 7

Chemical Properties

• Melting Point: 198.0 to 202.0 °C
• Appearance: /
• Solubility: soluble in Methanol
• BRN: 10500170
• CAS DataBase Reference: (4-Nitrophenyl)phenyliodonium trifluoromethanesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: (4-Nitrophenyl)phenyliodonium trifluoromethanesulfonate(905718-45-8)
• EPA Substance Registry System: (4-Nitrophenyl)phenyliodonium trifluoromethanesulfonate(905718-45-8)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26
• WGK Germany: 3
• Hazardous Substances Data: 905718-45-8(Hazardous Substances Data)

Usage

General Description

(4-Nitrophenyl)phenyliodonium trifluoromethanesulfonate is a chemical compound that is used as a source of the phenyliodonium cation in various organic reactions. It is specifically used as a reagent for oxidative transformations and as a source of electrophilic aromatic iodine species. (4-Nitrophenyl)phenyliodonium trifluoromethanesulfonate is known for its high stability and reactivity, and it is often utilized as a mild and selective reagent in organic synthesis. Additionally, it has been employed in the synthesis of various pharmaceuticals and agrochemicals due to its ability to facilitate carbon-carbon and carbon-heteroatom bond formations. Overall, (4-Nitrophenyl)phenyliodonium trifluoromethanesulfonate is a versatile and valuable reagent in organic chemistry.

Upstream product

• 636-98-6 p-nitrobenzene iodide 
• 2926-30-9 sodium triflate 
• 71-43-2 benzene 
• 1493-13-6 trifluorormethanesulfonic acid 
• 98-80-6 phenylboronic acid 
• 35895-70-6 tetrabutylammonium trifluoromethylsulfonate 
• 591-50-4 iodobenzene 
• 98-95-3 nitrobenzene 

Downstream Products

• 7418-39-5 N-(4-nitrophenyl)-N-phenylacetamide 
• 33672-82-1 N-(4-nitrophenyl)-N-methylbenzamide 
• 10252-51-4 1-(4-nitrophenyl)-3,5-diphenyl-1H-pyrazole 
• 100-25-4 para-dinitrobenzene 
• 100-02-7 4-nitro-phenol 
• 117635-44-6 tert-butyldimethyl(4-nitrophenoxy)silane 
• 35895-70-6 tetrabutylammonium trifluoromethylsulfonate 

Relevant articles and documents

Palladium(ii)-catalyzed stereoselective synthesis of: C-glycosides from glycals with diaryliodonium salts

An efficient palladium(ii) mediated C-glycosylation of glycals with diaryliodonium salts is described, providing a new strategy for the synthesis of 2,3-dideoxy C-Aryl glycosides with excellent stereoselectivity. The C-glycosylation of a diverse range of

Metal-Free C-Arylation of Nitro Compounds with Diaryliodonium Salts

An efficient, mild, and metal-free arylation of nitroalkanes with diaryliodonium salts has been developed, giving easy access to tertiary nitro compounds. The reaction proceeds in high yields without the need for excess reagents and can be extended to α-arylation of nitroesters. Nitroalkanes were selectively C-arylated in the presence of other easily arylated functional groups, such as phenols and aliphatic alcohols.

Reaction of iodoarenes with potassium peroxodisulfate/trifluoroacetic acid in the presence of aromatics. Direct preparation of diaryliodonium triflates from iodoarenes

Diaryliodonium triflates have been directly prepared by reaction of some iodoarenes with aromatic substrates in good yields by using K2S2O8/CF3COOH/CH2Cl2. Treatment of a variety of iodoare