33741-15-0

Usage

InChI:InChI=1/C8H12O2/c1-3-4-5-6-7-8(9)10-2/h3-5H,1,6-7H2,2H3/b5-4+

Upstream product

• 106-99-0 buta-1,3-diene 
• 292638-85-8 acrylic acid methyl ester 
• 922-65-6 divinylcarbinol 
• 78-39-7 Triethyl orthoacetate 
• 1445-45-0 Trimethyl orthoacetate 
• 41980-00-1 γ-vinyl-γ-valerolactone 
• 3236-44-0 vinyl-2 dihydro-2,3 4H-pyranne 
• 186581-53-3 diazomethane 
• 87238-57-1 (E)-9-carbomethohy-5-octenal 
• 81792-59-8 metilestere dell'acido 5-idrossi-6-n-eptenoico 

Downstream Products

• 116574-71-1 tert-butyl (3R)-3-(hydroxymethyl)piperidine-1-carboxylate 
• 194726-46-0 (3R)-3-formylpiperidine-1-carboxylic acid tert-butyl ester 
• 956253-09-1 C₁₄H₁₆N₄O₂S 

Relevant academic research and scientific papers

Synthesis of the A/E/F sections of conaconitine, napelline and related diterpenoid alkaloids of the aconitine group

The tricyclic amines (±)-2; R = H and R = Me with five stereogenic centres, representing the A/E/F ring system of the title alkaloids, have been synthesised from penta-1,4-dien-3-ol in eight (overall yield 20%) and nine steps (overall yield 16%) respectively.

An Expedient and Stereoselective Route to the Perhydrophenanthrene via Sequential Diels-Alder Reactions

A novel and efficient stereoselective synthesis of the perhydrophenanthrene skeleton was achieved using a sequential Diels-Alder cycloaddition strategy involving enyne 10 and bis-diene 8.

Efficient syntheses of the polyene fragments present in amphidinols

The C53-C67 and C53-C65 polyene fragments of amphidinols have been synthesized in an efficient and convergent fashion from sorbic acid in good overall yields (30-31%) by employing a chemoselective cross-metathesis of a Weinreb amide and a Julia-Kocienski

Cobalt mediated alkene/diene coupling; documentation of scope, limitations, and regioselectivity

The cobalt hydride catalyzed addition of alkenes bearing electron withdrawing groups to methylated 1,3-butadienes leads to functionalized hexadiene products.The reaction is limited to addends featuring at least one terminal alkene moiety.

Photochemistry of 2-Fluoro-2-alkylcyclohexanones. Drastic Effect of Fluorine Substitution

In the photreactions of 3-(2-oxocyclohexyl)-propionic acid derivatives 1 a pronounced effect of fluorine substitution is found on the ratio of a) Norrish II vs.Norrish I products; b) cyclization vs. cleavage of the Norrish II biradical; c) ketene vs. unsaturated aldehyde formation from the Norrish I biradical.