33756-42-2Relevant academic research and scientific papers
Triarylantimony(V) catecholates – Derivatives of 4,5-difluoro-3,6-di-tert-butyl-o-benzoquinone
Poddel'sky, Andrey I.,Smolyaninov, Ivan V.,Fukin, Georgy K.,Berberova, Nadezhda T.,Cherkasov, Vladimir K.,Abakumov, Gleb A.
, p. 1 - 6 (2016)
New triarylantimony(V) 4,5-difluoro-3,6-di-tert-butylcatecholates of (4,5-F2-3,6-Cat)SbAr3type, where Ar is p-fluorophenyl (1), p-chlorophenyl (2), phenyl (3), have been synthesized and characterized in details. The electrochemical p
Oxidative Cross-Coupling of Boron and Antimony Nucleophiles via Palladium(I)
Simpson, Quillon,Sinclair, Matthew J. G.,Lupton, David W.,Chaplin, Adrian B.,Hooper, Joel F.
supporting information, p. 5537 - 5540 (2018/09/21)
The use of an isolatable, monomeric Pd(I) complex as a catalyst for the oxidative cross-coupling of aryl-antimony and aryl-boron nucleophiles is reported. This reaction tolerates a wide variety of substrates, with >20:1 selectivity for cross-coupled products. This strategy offers a new approach to achieving the selective cross-coupling of nucleophiles.
Novel tetranuclear triarylantimony(v) complexes with (±)-mandelic acid ligands: Synthesis, characterization, in vitro cytotoxicity and DNA binding properties
Jiang, Jin,Yin, Handong,Wang, Fangli,Han, Zhong,Wang, Fei,Cheng, Shuang,Hong, Min
supporting information, p. 8563 - 8566 (2013/07/27)
Four novel tetranuclear organoantimony(v) complexes [R3SbL] 4, in which LH = (±)-mandelic acid and R = phenyl (1), 4-fluorophenyl (2), 3-fluorophenyl (3), 3,4,5-trifluorophenyl (4), were synthesized and characterized. The complexes displayed rapid, low micromolar in vitro cytotoxicity against a range of epithelial tumour cells and efficient CT-DNA binding.
TRIORGANOANTIMONY COMPOUNDS FOR PESTICIDAL USE
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Page/Page column 26; 27, (2008/06/13)
The invention concerns with synthesis of mixed triorganoantimony (III) compounds bearing halophenyl groups ("R2SbR1") , using metal turnings viz Lithium, Magnesium or Zinc in donor solvents with plurality of uses as microbiocides and insecticides for cont
Fourier-transform Raman and infrared spectra and normal coordinate analysis of the triphenyl compounds and their methyl-, methoxy- and fluoro-substituted derivatives of arsenic, antimony and bismuth
Ludwig,Dolny,Goetze
, p. 2363 - 2372 (2007/10/03)
The Fourier transform (FT)-Raman and infrared (IR) spectra of triphenyl-, perdeuterated triphenyl-, tris(2-methylphenyl)-, tris(3-methylphenyl)-, tris(2,4,6-trimethylphenyl)-, tris(2-methoxyphenyl)-, tris(3-methoxyphenyl)-, tris(3-fluorophenyl)- and tris(
Tri- and di-arylantimony( V) thiocyanates and mixed halide thiocyanates; crystal structure of triphenylantimony( V) di-isothiocyanate
Forster, Glynis E.,Begley, Michael J.,Sowerby, D. Bryan
, p. 263 - 274 (2007/10/03)
A series of triarylantimony(V) dithiocyanates has been prepared by oxidising the appropriate antimony(III) compound with thiocyanogen. IR and 14N NMR spectroscopy indicate the presence of terminally N-bonded thiocyanate groups and this has been confirmed by a crystal structure determination for the SbPh3(NCS)2. The asymmetric unit contains three independent trigonal bipyramidal molecules, which differ in the orientations of the axial N-bonded thiocyanates and the phenyl groups in the equatorial plane, and there may be weak C-H ... S interactions. Treatment of SbPh2X3, where X = Br or Cl, with KSCN gave K[SbPh2(NCS)4] and attempts to prepare SbPh2(NCS)3 and related diphenylantimony(V) mixed halide thiocyanates, SbPh2Xn(NCS)3 - n where X = Br or Cl and n = 0-2, by treating appropriate diphenylantimony(III) precursors with thiocyanogen or thiocyanogen bromide or chloride gave products which in many cases underwent reorganisation during recrystallisation. Samples of SbPh2(NCS)3, SbPh2Br(NCS)2, SbPh2Br2(NCS) and SbPh2Cl2(NCS), and SbPh3Br(NCS) have, however, been isolated as microcrystalline solids.
