338459-07-7

Upstream product

• 925932-26-9 6-(benzyloxy)-1,11-bis(tert-butyldiphenylsiloxy)-4,8-dioxaundecane-2,10-diol 
• 100-39-0 benzyl bromide 
• 53380-10-2 1,3-bis((2,2-dimethyl-1,3-dioxolan-4-yl)methoxy)propan-2-ol 
• 1107629-74-2 2,6,10-tris(benzyloxy)-1,11-bis(tert-butyldiphenylsiloxy)-4,8-dioxaundecane 
• 338459-05-5 10-O-benzyl-4,8,12,16-tetraoxanonadecane-1,18-diene-6,10,14-triol 
• 132735-04-7 glycerol-α,α'-diallyl ether 
• 196497-38-8 6-(benzyloxy)-4,8-dioxaundecane-1,2,10,11-tetraol 
• 334490-60-7 6-(benzyloxy)-1,2:10,11-bis(isopropylidenedioxy)-4,8-dioxaundecane 
• 338459-06-6 6,10,14-tri-O-benzyl-4,8,12,16-tetraoxanonadecane-1,18-diene-6,10,14-triol 
• 196497-40-2 6-O-benzyl-1,2:10,11-diepoxy-4,8-dioxaundecane-6-ol 
• 93625-24-2 6-O-benzyl-4,8-dioxaundecane-1,10-dien-6-ol 

Downstream Products

• 925932-27-0 C₄₄H₅₀O₁₁S₂ 
• 925932-29-2 2,6,10-O-tribenzyl-1-O-(4-toluenesulfonyl)-4,8-dioxaundecane-1,2,6,10,11-pentaol 
• 1107629-78-6 1,11-bis(arachidoyloxy)-2,6,10-tris(benzyloxy)-4,8-dioxaundecane 
• 1107629-76-4 2,6,10-tris(benzyloxy)-1,11-bis(mirystoyloxy)-4,8-dioxaundecane 
• 1107629-75-3 2,6,10-tris(benzyloxy)-1,11-bis(stearoyloxy)-4,8-dioxaundecane 
• 1107629-77-5 2,6,10-tris(benzyloxy)-1,11-bis(palmitoyloxy)-4,8-dioxaundecane 
• 1304788-36-0 1,5,9-O-tribenzyl-3,7,11-trioxacyclododecane-1,7,11-triol 
• 1304788-34-8 1,5,9-O-tribenzyl-3,7,11-trioxacyclododecane-1,7,11-triol 
• 338459-13-5 3,7,11,15,19-penta-O-benzyl-1,5,9,13,17-pentaoxacycloicosane-3,7,11,15,19-pentaol 
• 338459-11-3 3,7,11,15-tetra-O-benzyl-1,5,9,13-tetraoxacyclohexadecane-3,7,11,15-tetraol 
• 338459-09-9 3,7,11-tri-O-benzyl-1,5,9-trioxacyclododecane-3,7,11-triol 
• 925932-33-8 C₅₇H₆₈O₁₃S 
• 925932-32-7 C₅₀H₆₂O₁₁ 
• 925932-31-6 C₄₇H₅₆O₁₁S 

Relevant academic research and scientific papers

Synthesis of structurally weil-defined triglyceryl di-, tri-, and tetra-fatty acid esters as new oil gelators

We are interested in developing chemically modified linear and cyclic polyglycerols and their esters that have a single polymerization degree and fine structure. Triglyceryl di-, tri-, and tetra-fatty acid esters were synthesized from common substrate as new prominent gelators. The triglyceryl esters were capable of gelling up cooking oils. A comparison of the gelation ability of structurally related compounds clarified that the introduction of alkyl chains of suitable length is required for effective gelation. Georg Thieme Verlag Stuttgart · New York.

Synthesis of cyclic polyglycerols

Authentic standards of cyclic polyglycerol, with well-defined structures and degrees of polymerization from 3 to 6 cyclic oligomers, have been efficiently synthesized. The intramolecular cyclization conditions gave cyclic glycerols more effectively than intermolecular coupling conditions.

Original synthesis of linear, branched and cyclic oligoglycerol standards

A variety of authentic standards of linear, branched and cyclic oligomers of glycerol, with well-defined structures and degrees of polymerisation from 2 to 5, have been efficiently synthesised. Linear oligomers were obtained by means of a convergent approach based on regioselective opening of bis(epoxides) with solketal; branched compounds were synthesised using oxidative cleavage of the corresponding anhydrohexitols as the key step. A 6-exo-trig halocyclisation reaction involving heteroatom-tethered unsaturated alcohols permitted an efficient synthesis of the precursors of selected cyclic dimers; larger cyclic oligomers were prepared by two one-pot Williamson reactions using a ditriflate derived from diglycerol. All these methodologies permitted further scaling up.