3395-82-2

Basic information

• Product Name: para-tert.-Butylbenzaldehyddimethylacetal
• Synonyms: para-tert.-Butylbenzaldehyddimethylacetal
• CAS NO: 3395-82-2
• Molecular Formula: C₁₃H₂₀O₂
• Molecular Weight: 208.3
• Mol File: 3395-82-2.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 245.464°C at 760 mmHg
• Flash Point: 74.734°C
• Appearance: /
• Density: 0.951g/cm³
• Vapor Pressure: 0.045mmHg at 25°C
• Refractive Index: 1.481
• CAS DataBase Reference: para-tert.-Butylbenzaldehyddimethylacetal(CAS DataBase Reference)
• NIST Chemistry Reference: para-tert.-Butylbenzaldehyddimethylacetal(3395-82-2)
• EPA Substance Registry System: para-tert.-Butylbenzaldehyddimethylacetal(3395-82-2)

Safety Data

• Hazardous Substances Data: 3395-82-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H20O2/c1-13(2,3)11-8-6-10(7-9-11)12(14-4)15-5/h6-9,12H,1-5H3

Upstream product

• 67-56-1 methanol 
• 98-51-1 4-tert-butyltoluene 
• 939-97-9 4-tert-Butylbenzaldehyde 
• 149-73-5 trimethyl orthoformate 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 115-11-7 isobutene 
• 100-52-7 benzaldehyde 
• 88001-42-7 benzyl 2-methoxypyrrolidine-1-carboxylate 

Downstream Products

• 120254-43-5 3-[(4-tert-Butyl-phenyl)-methoxy-methyl]-2-methoxy-tetrahydro-pyran 
• 26537-19-9 methyl 4-tert-butylbenzoate 
• 104865-87-4 trimethyl 4-tert-butylorthobenzoate 
• 939-97-9 4-tert-Butylbenzaldehyde 
• 18127-01-0 3-(4-tert-butylphenyl)propionaldehyde 
• 84434-23-1 3-(4-(tert-butyl)phenyl)acrylaldehyde 
• 149550-23-2 2-(4-(tert-butyl) benzylidene) malononitrile 
• 1434139-85-1 (E)-ethyl 5-(4-tert-butylphenyl)-3,5dimethoxypent-2-enoate 

Relevant articles and documents

Method for synthesizing 4-tert-butyl benzaldehyde

The invention discloses a method for synthesizing 4-tert-butyl benzaldehyde and belongs to the technical field of organic synthesis. The method comprises the steps of subjecting benzaldehyde and triorthoformate to a reaction to produce benzaldehyde acetal, then, subjecting the benzaldehyde acetal and isobutene to a sealed reaction in the presence of a catalyst, and carrying out acid quenching, thereby obtaining the 4-tert-butyl benzaldehyde. According to the method, the 4-tert-butyl benzaldehyde is obtained through adopting benzaldehyde protection, then, firstly, becoming an electron donatingorientating group, and then, prompting selective localization of the isobutene by employing an appropriate catalyst; and a ratio of a 2-tert-butyl benzaldehyde isomer to the product is smaller than 1:14, and after the reaction ends up, the process is applicable to industrialized large-scale production.

P- tert-Butyl Groups Improve the Utility of Aromatic Protecting Groups in Carbohydrate Synthesis

Aromatic protective groups are widely used in carbohydrate synthesis owing to their numerous merits. However, they unpredictably make certain compounds insoluble in organic solvents owing to their π-stacking abilities. It was found that introducing a tert

Electrochemical deallylation of α-allyl cyclic amines and synthesis of optically active quaternary cyclic amino acids

Electrochemical oxidation of α-allylated and α-betizylated N-acylated cyclic amines by using a graphite anode easily affords the corresponding α-methoxylated products with up to 76% yield. Ease of oxidation was affected by the type of electrode, the size