34341-29-2

Basic information

• Product Name: Benzaldehyde, 2,3,6-trimethyl- (6CI,8CI,9CI)
• Synonyms: Benzaldehyde, 2,3,6-trimethyl- (6CI,8CI,9CI)
• CAS NO: 34341-29-2
• Molecular Formula: C₁₀H₁₂O
• Molecular Weight: 148.20168
• Product Categories: ALDEHYDE
• Mol File: 34341-29-2.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzaldehyde, 2,3,6-trimethyl- (6CI,8CI,9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 2,3,6-trimethyl- (6CI,8CI,9CI)(34341-29-2)
• EPA Substance Registry System: Benzaldehyde, 2,3,6-trimethyl- (6CI,8CI,9CI)(34341-29-2)

Safety Data

• Hazardous Substances Data: 34341-29-2(Hazardous Substances Data)

Upstream product

• 95-87-4 2,5-Dimethylphenol 
• 13061-96-6 dihydroxy-methyl-borane 
• 1403381-95-2 2-formyl-3,6-dimethylphenyl trifluoromethanesulfonate 
• 1666-04-2 2-hydroxy-3,6-dimethylbenzaldehyde 
• 35044-59-8 2,6,6-trimethyl-1,3-cyclohexadiene-1-carboxylic acid ethyl ester 
• 76964-13-1 2-formyl-3,4-dihydro-5,8-dimethylnaphthalene 
• 124211-40-1 4-(2,3,6-trimethylphenyl)-3-bromobutan-2-one 
• 124211-43-4 4-(2-Hydroxymethyl-3,6-dimethyl-phenyl)-butan-2-ol 
• 124211-42-3 4-(3,6-dimethyl-2-formylphenyl)butan-2-one 
• 66248-70-2 4-(2,3,6-trimethyl-phenyl)-butan-2-ol 
• 58720-40-4 4-(2,3,6-trimethyl-phenyl)-butan-2-one 
• 30316-18-8 1,2-dihydro-3,5,8-trimethyl-naphthalene 
• 122-51-0 orthoformic acid triethyl ester 
• 4436-51-5 1-hydroxymethyl-2,6,6-trimethylcyclohexa-1,3-diene 

Downstream Products

• 108773-90-6 4-Methyl-6-(2',3',6'-trimethyl-phenyl)-hexen-⁽⁵⁾-in-⁽¹⁾-ol-⁽⁴⁾ 
• 524-01-6 isorenieratene 
• 54756-73-9 (2,3,6-trimethylbenzyl)triphenylphosphonium bromide 
• 4382-02-9 trans-β-isorenieratene 
• 58720-40-4 4-(2,3,6-trimethyl-phenyl)-butan-2-one 
• 108719-74-0 4t-(2,3,6-trimethyl-phenyl)-but-3-en-2-one semicarbazone 
• 18237-73-5 (2,3,6-trimethylphenyl)methyl alcohol 
• 2529-36-4 2,3,6-trimethylbenzoic acid 
• 56681-06-2 4-<2,3,6-Trimethyl-phenyl-(1)>-buten-(3)-on-(2) 
• 115189-16-7 1,5-Bis-<2',3',6'-trimethyl-phenyl>-pentadien-(1,4)-on-(3) 
• 73225-00-0 (1E,4E)-1-tert-Butylsulfanyl-5-(2,3,6-trimethyl-phenyl)-penta-1,4-dien-3-one 
• 57461-21-9 (3E)-4-(2,3,6-trimethylphenyl)but-3-en-2-one 
• 115189-16-7 1t,5t-bis-(2,3,6-trimethyl-phenyl)-penta-1,4-dien-3-one 

Relevant articles and documents

One-step, stereoselective synthesis of octahydrochromanes via the Prins reaction and their cannabinoid activities

Novel, functionalized octahydrochromane derivatives were synthesized in a single step via the Prins reaction. Enantiomerically pure (+)-isopulegol was reacted with benzaldehyde to stereoselectively yield the corresponding octahydro-2H-chromen-4-ol derivative containing five stereocenters. A total of 10 compounds were synthesized by altering the enantiomer of isopulegol and the substituted benzaldehyde, and the resulting enantiopure octahydrochromanes were screened in vitro against the cannabinoid receptor isoforms CB1 and CB2. Compounds containing an olefin at the C4 position [(+)-3c, (?)-3c, (?)-7c, (?)-9c and (?)-11c] of the octahydrochromane scaffold were found to exhibit reasonable displacement of [3H] CP55,940 from the CB receptors, whereas the corresponding hydroxy analogs [(+)-3a, (+)-3b, (?)-3a, (?)-3b and (+)-5a] had very little or no effect.

A new synthesis of 4-(2,3,6-trimethylphenyl)butan-2-ol, a C13-norisoprenoid artifact from Vitis vinifera linn. and its conversion to several terpenic natural products of plant and marine origin

The four-step synthesis of 4-(2,3,6-trimethylphenyl)butan-2-ol (1), starts from 5,8-dimethyl-3,4-dihydro-2-naphthaldehyde (2).The trimethyldihydronaphthalene (10) obtained from the reduction of 2 is ozonised to the keto aldehyde (11), which is reduced to