34591-97-4

Upstream product

• 19790-60-4 3-Benzyloxypropanal 
• 149-73-5 trimethyl orthoformate 
• 5470-84-8 4-benzyloxybutanal 
• 67-56-1 methanol 
• 4799-68-2 3-benzyloxypropan-1-ol 
• 107-02-8 acrolein 
• 100-51-6 benzyl alcohol 

Downstream Products

• 133625-45-3 (1'RS)-1-(3'-Benzyloxy-1'-methoxypropyl)uracil 
• 133625-55-5 (1'RS)-1-(3'-Benzyloxy-1'-methoxypropyl)-5-fluorouracil 
• 34591-98-5 6-Benzyloxy-3-hexen-2-on 
• 189195-74-2 (4R,6R)-4,6-Diallyl-2-(2-benzyloxy-ethyl)-[1,3]dioxane 
• 1400585-73-0 (S)-N-[(2R,3R)-4-benzyloxy-3-methoxy-2-pivaloyloxypentanoyl]-4-isopropyl-1,3-thiazolidine-2-thione 
• 1400585-93-4 ethyl (4R,5R)-7-benzyloxy-5-methoxy-2,2-dimethyl-3-oxo-4-pivaloyloxyheptanoate 
• 1124308-86-6 C₂₀H₂₉NO₃S₂ 
• 189195-77-5 [(2R,4S,6S)-2-(2-Benzyloxy-ethyl)-6-((4S,6R)-6-bromomethyl-2,2-dimethyl-[1,3]dioxan-4-ylmethyl)-tetrahydro-pyran-4-yloxy]-tert-butyl-dimethyl-silane 
• 189195-80-0 C₆₆H₁₀₈N₂O₁₁Si₂ 
• 189195-78-6 (4S,6S)-4-{(4R,6S)-6-[(2S,4S,6R)-6-(2-Benzyloxy-ethyl)-4-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-ylmethyl]-2,2-dimethyl-[1,3]dioxan-4-ylmethyl}-2,2-dimethyl-6-triisopropylsilanyloxymethyl-[1,3]dioxane-4-carbonitrile 
• 189195-79-7 (4S,6S)-4-{(4R,6S)-6-[(2S,4S,6R)-6-(2-Benzyloxy-ethyl)-4-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-ylmethyl]-2,2-dimethyl-[1,3]dioxan-4-ylmethyl}-6-iodomethyl-2,2-dimethyl-[1,3]dioxane-4-carbonitrile 
• 189195-75-3 Acetic acid (2S,4S,6R)-2-((R)-2-acetoxy-pent-4-enyl)-6-(2-benzyloxy-ethyl)-tetrahydro-pyran-4-yl ester 

Relevant academic research and scientific papers

Two-way homologation of aliphatic aldehydes: Both one-carbon shortening and lengthening via the same intermediate

Aliphatic aldehydes can be homologated to both one-carbon shorter and one-carbon longer homologous carbonyl compounds through the 2–4 steps of reactions via the same intermediates, β,γ-unsaturated α-nitrosulfones, prepared from the proline-catalyzed sequential reactions of several aliphatic aldehydes with phenylsulfonylnitromethane. While the oxidative cleavage of the key intermediates gave one-carbon less homologous carbonyl compounds, the reduction of the same key intermediates followed by an oxidation produced one-carbon more homologous carbonyl compounds.

Photo-organocatalytic synthesis of acetals from aldehydes

A mild and green photo-organocatalytic protocol for the highly efficient acetalization of aldehydes has been developed. Utilizing thioxanthenone as the photocatalyst and inexpensive household lamps as the light source, a variety of aromatic and aliphatic aldehydes have been converted into acyclic and cyclic acetals in high yields. The reaction mechanism was extensively studied.

Novel σ1 receptor ligands by oxa-pictet-spengler reaction of pyrazolylethanol

The oxa-Pictet-Spengler reaction of 2-(1-phenylpyrazol-5-yl)ethanol required the weak acid pyridinium p-toluenesulfonate to provide pyrano[4,3-c]pyrazoles with additional functional groups in the side chain. These functional groups allow the introduction

Remote Asymmetric Induction in Diastereoface Selective Addition Reactions of Optically Active α-Substituted-β-silyl (E)-Hexenoates with Achiral α-Alkoxy and β-Alkoxy Acetals

Optically active and diastereomerically pure (E)-crotylsilanes 1 function as effective chiral carbon nucleophiles in trimethylsilyl trifluoromethanesulfonate (TMSOTf) catalyzed asymmetric addition reactions of achiral, α-alkoxy and β-alkoxy acetals 2, res