345967-22-8

Basic information

• Product Name: 3,4-a']dinaphthalen-4-yl)dimethylamine
• Synonyms: (±)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;(±)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)dimethylamine;3,4-a']dinaphthalen-4-yl)dimethylamine (±)-MonoPhos
• CAS NO: 345967-22-8
• Molecular Formula: C₂₂H₁₈NO₂P
• Molecular Weight: 359.357581
• EINECS: -0
• Mol File: 345967-22-8.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 548.7±33.0 °C(Predicted)
• Appearance: /
• Storage Temp.: 2-8°C
• PKA: 1.22±0.20(Predicted)
• CAS DataBase Reference: 3,4-a']dinaphthalen-4-yl)dimethylamine(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4-a']dinaphthalen-4-yl)dimethylamine(345967-22-8)
• EPA Substance Registry System: 3,4-a']dinaphthalen-4-yl)dimethylamine(345967-22-8)

Safety Data

• Hazardous Substances Data: 345967-22-8(Hazardous Substances Data)

Usage

General Description

3,4-a']dinaphthalen-4-yl)dimethylamine is a chemical compound with the molecular formula C20H17N. It is a member of the amine class of organic compounds and contains two different aromatic rings. This chemical is primarily used as a building block in the synthesis of various pharmaceuticals and organic compounds. It is also known for its potential application as a ligand in organometallic chemistry. Additionally, 3,4-a']dinaphthalen-4-yl)dimethylamine has been studied for its potential biological activity, including its role in the development of new drugs and therapies. As a result, this chemical compound is of interest to researchers and scientists in the fields of chemistry, pharmacology, and medicine.

Upstream product

• 137156-22-0 binaphthol chlorophosphite 
• 124-40-3 dimethyl amine 
• 1608-26-0 Hexamethylphosphorous triamide 
• 602-09-5 1,1'-bi-2-naphthol 

Downstream Products

• 1158177-79-7 [Rh(cyclooctadiene)((S)-(+)-(3,5-dioxa-4-phosphacyclohepta[2,1-a;3,4-a']-dinaphthalen-4-yl)dimethylamine)(P(C₆H₅)3)]BF₄ 
• 1158177-81-1 [Rh(cyclooctadiene)((S)-(+)-(3,5-dioxa-4-phosphacyclohepta[2,1-a;3,4-a']-dinaphthalen-4-yl)dimethylamine)(P(C₆H₅)2C₇H₇N₂O)]BF₄ 

Relevant articles and documents

Palladium-Catalyzed Diastereoselective Synthesis of (Z)-Conjugated Enynyl Homoallylic Alcohols

The diastereoselective synthesis of anti-homoallylic alcohols bearing conjugated (Z)-enynes through a palladium-catalyzed three-component reaction is described. This reaction features a broad substrate scope, good functional group compatibility, and high levels of (Z)-alkene stereocontrol. In this reaction, Pd(0) functions as a catalyst in two fundamental steps of the tandem sequence: 1) the generation of a borylated π-allylpalladium species from bifunctional conjunctive reagents, inducing umpolung allylation of aldehydes, and 2) C(sp2)?C(sp) cross-coupling. Further transformations of the obtained products highlight their synthetic utility. (Figure presented.).

Synthesis of Chiral Phosphorus Reagents and Their Catalytic Activity in Asymmetric Borane Reduction of N-Phenyl Imine of Acetophenone

Eleven chiral trivalent or quatrivalent phosphorus reagents were synthesized starting from L-proline, D-camphor, (+)- or (-)-1,1'-binaphthalene-2,2'-diol, (-)-α-phenylethylamine, etc. and their application as catalysts in asymmetric borane reduction of N-