34649-15-5Relevant academic research and scientific papers
β-Phenylselenoethanol, an efficient reagent for the one-pot synthesis of aryl vinyl ethers
Fu, Gui-Yun,Yu, La-Mei,Mao, Xue-Chun,Wu, Dan
, p. 595 - 597 (2008)
β-Phenylselenoethanol was treated with phenols under Mitsunobu conditions and subsequent oxidation-elimination with 30% hydrogen peroxide furnished aryl vinyl ethers with good yields (85-90%) in a one-pot, two-step transformation.
Solid-phase organic synthesis of aryl vinyl ethers using sulfone-linking strategy
Yu, Lamei,Tang, Ni,Sheng, Shouri,Chen, Rubing,Liu, Xiaoling,Cai, Mingzhong
experimental part, p. 1027 - 1030 (2012/07/28)
A novel facile solid-phase organic synthesis of aryl vinyl ethers by reaction of polystyrene-supported 2-phenylsulfonylethanol with phenols under Mitsunobu conditions and subsequent elimination reaction with DBU has been developed. The advantages of this method include straightforward operation, good yield and high purity of the products. Alternatively, a typical example of Suzuki coupling reaction on-resin was further applied to prepare 4-phenylphenyl vinyl ether for extending this method.
Solid-Phase synthesis of aryl vinyl ethers based on polystyrenesupported aβ-phenylselenoethanol
Zhang, Jia-Li,Sheng, Shou-Ri,Liub, Xue,Lin, Shu-Ying
experimental part, p. 287 - 289 (2010/02/28)
A novel facile solid-phase organic synthesis of aryl vinyl ethers by reaction of polystyrene-supported β-phenylselenoethanol with phenols under Mitsunobu conditions and subsequent oxidation-elimination with 30% hydrogen peroxide has been developed. The ad
Polymer-supported β-bromoethyl selenide: An efficient reagent for the synthesis of aryl vinyl ethers
Sheng, Shou-Ri,Liu, Xiao-Ling,Wang, Xing-Cong,Xin, Qin,Song, Cai-Sheng
, p. 2833 - 2836 (2007/10/03)
A simple and efficient procedure for the solid-phase synthesis of aryl vinyl ethers using polymer-supported β-bromoethyl selenide with traceless linker strategy is described.
VINYLOXYBENZENEDIAZONIUM CHLORIDE IN AZO COUPLING AND IN EXCHANGE OF THE DIAZO GROUP WITH NUCLEOPHILIC REAGENTS
Stepanova, Z. V.,Grebneva, P. I.,Skvortsova, G. G.
, p. 1495 - 1498 (2007/10/02)
In the reaction of vinyloxybenzenediazonium ion with aromatic amines conditions were found for the C-coupling reaction in an aqueous methanol medium, and a series of new amino- and dialkylamino-substituted vinyl ethers of azobenzenes were synthesized.Treatment of solutions of vinyloxybenzenediazonium chloride with copper chlorides or cyanides leads to the addition of Cl- or CN- in the aromatic ring with the elimination of nitrogen, and the reaction of vinyloxybenzenediazonium ion with the chloride ion is complicated by side processes in the vinyloxy group.A method is developed for the synthesis of m- and p-vinyloxycyanobenzenes.
