34714-00-6

Basic information

• Product Name: 6-CHLORO-1-TRIMETHYLSILYLOXYHEXANE
• Synonyms: 6-CHLORO-1-TRIMETHYLSILYLOXYHEXANE;[(6-Chlorohexyl)oxy]trimethylsilane;6-CHLORO-1-TRIMETHYLSILYLOXYHEXANE, 97%,
• CAS NO: 34714-00-6
• Molecular Formula: C₉H₂₁ClOSi
• Molecular Weight: 208.8
• Mol File: 34714-00-6.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 127 °C
• Flash Point: 71.4°C
• Appearance: /
• Density: 0.929
• Vapor Pressure: 0.213mmHg at 25°C
• Refractive Index: 1.425
• CAS DataBase Reference: 6-CHLORO-1-TRIMETHYLSILYLOXYHEXANE(CAS DataBase Reference)
• NIST Chemistry Reference: 6-CHLORO-1-TRIMETHYLSILYLOXYHEXANE(34714-00-6)
• EPA Substance Registry System: 6-CHLORO-1-TRIMETHYLSILYLOXYHEXANE(34714-00-6)

Safety Data

• Hazardous Substances Data: 34714-00-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H21ClOSi/c1-12(2,3)11-9-7-5-4-6-8-10/h4-9H2,1-3H3

Upstream product

• 2009-83-8 6-chloro-1-hexanol 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 629-11-8 1,6-hexanediol 
• 10416-59-8 N,O-bis-(trimethylsilyl)-acetamide 
• 75-77-4 chloro-trimethyl-silane 
• 10416-58-7 N,N-bis(trimethylsilyl)acetamide 

Downstream Products

• 33956-49-9 (8E,10E)-dodeca-8,10-dienol 

Relevant articles and documents

Synthesis method of laspeyresia pomonella sex pheromone

The invention relates to a synthesis method of laspeyresi pomonella sex pheromone. The method comprises the steps as follows: (1) methanol is added to methyl sorbate as a raw material, and an intermediate A sorbic alcohol is obtained through 5% palladium-carbon catalytic hydrogenation reduction; (2) the intermediate A sorbitol obtained in (1) and acetic anhydride are subjected to a reaction in ethyl acetate, triethylamine and water to obtain an intermediate B sorbic acetate; (3) 6-chlorohexanol is subjected to a reaction with trimethylchlorosilane in toluene in the presence of ethyl acetate and triethylamine, after the reaction, water is added, stirring and layering are performed, and an intermediate C6-chlorohexanol trimethylsilyl ester is obtained; (4) the intermediate B sorbic acetate and the intermediate C6-chlorohexanol trimethylsilyl ester are subjected to a reaction with sodium sand in a toluene solution, then, water and sulfuric acid are dropwise added, layering and rectification are performed, and a target product E8,E10-dodecadiene-1-ol is obtained. The synthesis method has the advantages as follows: the laspeyresi pomonella sex pheromone is synthesized from available rawmaterials, the reaction route is short, and the selectivity and product yield can be increased.

Zinc mediated reactions in organic synthesis: Efficient synthesis of silyl ethers under mild conditions

General and practical method for the syn the sis of silyl ethers in the presence of zinc powder under mild conditions has been described.

Carbofunctional silacyclobutanes 1. Synthesis of 1-(ω-hydroxyalkyl)silacyclobutanes

A four-step synthesis of 1-(ω-hydroxyalkyl)- and 1-(4-hydroxyphenyl)silacyclobutanes was carried out. The influence of the structure of the initial compounds and the reaction conditions on the ratio of the reaction products formed was studied. The stabili