352-15-8Relevant articles and documents
Solution Dynamics of Redox Noninnocent Nitrosoarene Ligands: Mapping the Electronic Criteria for the Formation of Persistent Metal-Coordinated Nitroxide Radicals
Barnett, Brandon R.,Labios, Liezel A.,Moore, Curtis E.,England, Jason,Rheingold, Arnold L.,Wieghardt, Karl,Figueroa, Joshua S.
, p. 7110 - 7121 (2015)
(Graph Presented) The redox-noninnocence of metal-coordinated C-organo nitrosoarenes has been established on the basis of solid-state characterization techniques, but the solution-phase properties of this class of metal-coordinated radicals have been rela
Ipso-Nitrosation of arylboronic acids with chlorotrimethylsilane and sodium nitrite
Prakash, G.K. Surya,Gurung, Laxman,Schmid, Philipp Christoph,Wang, Fang,Thomas, Tisa Elizabeth,Panja, Chiradeep,Mathew, Thomas,Olah, George A.
, p. 1975 - 1978 (2014/04/03)
Nitroso compounds are versatile reagents in synthetic organic chemistry. Herein, we disclose a feasible protocol for the ipso-nitrosation of aryl boronic acids using chlorotrimethylsilane-sodium nitrite unison as nitrosation reagent system.
Structural investigations of C-nitrosobenzenes. Part 1. Solution state 1H NMR studies
Fletcher, Daniel A.,Gowenlock, Brian G.,Orrell, Keith G.
, p. 2201 - 2205 (2007/10/03)
Ambient and low temperature 1H NMR spectra of a wide range of 3- and 4-monosubstituted, and some di- and tri-substituted C-nitrosobenzenes have enabled -N=O substituent constants for the static and rotating ring molecules to be calculated. This has provided information on the shielding anisotropy of the N=O group which in turn leads to the firm identification of the monomeric and dimeric solution species. In all cases lowering the solution temperature enhances the relative populations of dimers to monomers, with the (Z)-azodioxy dimer being preferred over the (E)-form, irrespective of the nature of the solid state dimeric structure.