35469-22-8Relevant articles and documents
Mass Spectral Studies of Alkylbenzenesulphonic Acids Through Their S-Benzylisothiouronium Salts
Borthakur, Arun,Rao, V. S. Bhaskar
, p. 48 - 54 (2007/10/02)
The mass spectra of alkylbenzenesulphonic acids in the form of their S-benzylisothiouronium salts have been studied.These S-benzylisothiouronium salts dissociated into two parent reactant ions: (i) alkylbenzenesulphonic acid and (ii) S-benzylisothiourea.The characteristic fragmentation patterns of alkylbenzenesulphonic acids (0-5 substituted alkyls) were studied and compared with those of the parent ion peak hydrocarbons.The intensity of the molecular decreased with the increase in the molecular weight of the sulphonic acids.Desulphonation as well as loss of the alkyl group was observed in all the spectra.Migration of the alkyl group from S to 0, followed by degradation, was also observed in all the spectra studied.
SULFENYL CHLORIDES, XIV; THE REACTION OF ARYLTHIOSULFONATES WITH ARYLSULFENYL HALIDES
Lazar, J.,Vinkler, E.
, p. 171 - 174 (2007/10/02)
Utilizing partial results published earlier , the sulfenylation reaction of aromatic thiolsulfonates was investigated.Aromatic thiolsulfonates rapidly react with sulfenyl bromide in acetonitrile solution, whereas with sulfenyl chloride the splitting of the thiolsulfonate bond proceeds only in dimethylformamide and under forceful conditions.