354816-38-9Relevant academic research and scientific papers
Carbene-Catalyzed Enantioselective Hydrophosphination of α-Bromoenals to Prepare Phosphine-Containing Chiral Molecules
Chai, Huifang,Chi, Yonggui Robin,Jin, Zhichao,Maiti, Rakesh,Mondal, Bivas,Xu, Jun,Yan, Jia-Lei,Yang, Xing
supporting information, p. 26616 - 26621 (2021/11/10)
Disclosed herein is the first carbene-organocatalyzed asymmetric addition of phosphine nucleophiles to the in situ generated α,β-unsaturated acyl azolium intermediates. Our reaction enantioselectively constructs carbon–phosphine bonds and prepares chiral
Palladium-catalyzed 1,4-addition of diarylphosphines to α,β-unsaturated N-acylpyrroles
Du, Dan,Duan, Wei-Liang
, p. 11101 - 11103 (2011/11/05)
Highly stereoselective asymmetric 1,4-addition of diarylphosphines to α,β-unsaturated N-acylpyrroles catalyzed by a PCP pincer-Pd complex has been developed for the synthesis of chiral phosphines with excellent stereoselectivity (91-99% ee) under mild con
