216863-12-6Relevant articles and documents
Palladium-catalyzed 1,4-addition of diarylphosphines to α,β-unsaturated N-acylpyrroles
Du, Dan,Duan, Wei-Liang
, p. 11101 - 11103 (2011/11/05)
Highly stereoselective asymmetric 1,4-addition of diarylphosphines to α,β-unsaturated N-acylpyrroles catalyzed by a PCP pincer-Pd complex has been developed for the synthesis of chiral phosphines with excellent stereoselectivity (91-99% ee) under mild con
A modular approach to ligands for asymmetric π-allyl palladium catalysed additions
Gilbertson, Scott R.,Chang, Cheng-Wei T.
, p. 975 - 976 (2007/10/03)
A route to phosphinodihydrooxazoles is reported, which is used to synthesize ten new ligands whose ability to asymmetrically catalyse the addition of dimethyl malonate to 1,3-diphenylprop-2-enyl acetate is investigated; the best gave a palladium complex w