192371-97-4

Upstream product

• 4070-48-8 L-Valine methyl ester 
• 949013-80-3 3-phenyl-1-pyrrol-1-yl-2-propen-1-one 
• 829-85-6 diphenylphosphane 
• 216863-12-6 C₂₆H₃₀NO₂PS 
• 216862-91-8 C₂₇H₃₀NO₃PS 
• 1334387-79-9 C₂₅H₂₂NOPS 
• 354816-38-9 (S)-3-(diphenylphosphorothioyl)-3-phenylpropanoic acid 
• 192371-88-3 (S)-2-[3-(Diphenyl-phosphinothioyl)-3-phenyl-propionylamino]-3-methyl-butyric acid methyl ester 
• 192371-81-6 3-(Diphenyl-phosphinothioyl)-3-phenyl-propionic acid 
• 216863-12-6 (R)-3-(Diphenyl-phosphinothioyl)-N-((S)-1-hydroxymethyl-2-methyl-propyl)-3-phenyl-propionamide 

Downstream Products

• 192372-08-0 C₂₆H₂₈NOP 

Relevant academic research and scientific papers

Palladium-catalyzed 1,4-addition of diarylphosphines to α,β-unsaturated N-acylpyrroles

Highly stereoselective asymmetric 1,4-addition of diarylphosphines to α,β-unsaturated N-acylpyrroles catalyzed by a PCP pincer-Pd complex has been developed for the synthesis of chiral phosphines with excellent stereoselectivity (91-99% ee) under mild con

Synthesis of phosphino oxazoline ligand libraries from amino acid and phosphino carboxylate building blocks

A modular route to new phosphine-oxazoline ligands is reported. The ability of these ligands to asymmetrically catalyze the addition of dimethyl malonate to 1,3-diphenylprop-2-enyl acetate was investigated. The best of these ligands gave a palladium complex which catalyzed the addition of dimethyl malonate to 1,3-diphenylprop-2-enyl acetate in a 99% yield and in 98% enantiomeric excess (Table 3, entry 11).

A modular approach to ligands for asymmetric π-allyl palladium catalysed additions

A route to phosphinodihydrooxazoles is reported, which is used to synthesize ten new ligands whose ability to asymmetrically catalyse the addition of dimethyl malonate to 1,3-diphenylprop-2-enyl acetate is investigated; the best gave a palladium complex w