35532-73-1Relevant articles and documents
THERMOLYSIS OF 6-HYDROXYIMINO-1,3,5-TRI-t-BUTYL-5-METHYL-1,3-CYCLOHEXADIENE
Okazaki, Renji,Watanabe, Masako,Inamoto, Naoki
, p. 959 - 960 (1982)
Mechanism of the thermolysis of the title compound has been proposed, which begins with a homolytic cleavage leading to t-butyl radical and 2,4-di-t-butyl-6-methyl-1-nitrosobenzene.The reaction of the nitrosobenzene with t-butyl radical generated from photolysis of 2,2'-dimethyl-2,2'-azopropane is also described.
Atropisomerism in Diarylamines: Structural Requirements and Mechanisms of Conformational Interconversion
Clayden, Jonathan,Costil, Romain,Duarte, Fernanda,Sterling, Alistair J.
, p. 18670 - 18678 (2020/08/25)
In common with other hindered structures containing two aromatic rings linked by a short tether, diarylamines may exhibit atropisomerism (chirality due to restricted rotation). Previous examples have principally been tertiary amines, especially those with
1,3-CYCLOADDITIONS OF A THIONITROSO S-SULFIDE
Huisgen, Rolf,Peng, Xia
, p. 6063 - 6066 (2007/10/02)
The thionitroso S-sulfide 5 adds to (E)-cyclooctene, (E,Z)-1,5-cyclooctadiene, and norbornene to give 1,2,3-dithiazolidines, whereas enamines undergo electrophilic substitution.
N-aryl-N'-(cyclo)-alkyl-thioureas and their use as agents for combating animal pests and plant pests
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, (2008/06/13)
N-Aryl-N'-(cyclo)-alkyl-thioureas of the formula STR1 in which R1 represents alkyl-(C1 -C6) or cycloalkyl-(C3 -C7), R2 represents alkyl-(C2 -C6) or cycloalkyl-(C3 -C7), R3 represents alkyl-(C1 -C6), alkenyl-(C3 -C6), cycloalkyl-(C3 -C7), cycloalkenyl-(C5 -C7) or halogen, n represents 0, 1 or 2, and R7 represents optionally substituted cycloalkyl-(C3 -C10), optionally substituted cycloalkenyl-(C5 -C10) or the radical STR2 in which R4 represents hydrogen, alkyl-(C1 -C6) or cycloalkyl-(C3 -C7) and R5 and R6 may be identical or different and represent alkyl-(C1 -C6) or cycloalkyl-(C3 -C7), and acid addition salts thereof, are useful for their ectoparasiticidal, insecticidal, fungicidal and acaricidal effects. These compounds may be produced, inter alia, by reacting aryl isothiocyanates of the formula STR3 with amines of the formula H2 N--R7.
Chemistry of N-Thiosulfinylanilines. V. Reactions of N-Thiosulfinylanilines with Nucleophilic Reagents
Inagaki, Yoshio,Hosogai, Takeo,Okazaki, Renji,Inamoto, Naoki
, p. 205 - 209 (2007/10/02)
2,4-Di-t-butyl-6-methyl-N-(thiosulfinyl)aniline (1) gave 2,4-di-t-butyl-6-methylaniline in the reactions with such reagents as alkylamines, thiourea, butyllithium, alkylmagnesium halides, 1-(1-pyrrolidinyl)cyclopentene, and hydrogen sulfide.Triphenylphosphine reacted with 1 to give (2,4-di-t-butyl-6-methylphenylimino)triphenylphosphorane and bis(2,4-di-t-butyl-6-methylphenyl)sulfur diimide.Reaction of triphenylphosphine with 2,4,6-tri-t-butyl-7,8-dithia-9-azabicyclonona-2,4,9-triene afforded 2,4,6-tri-t-butylaniline, bis(2,4,6-tri-t-butylphenyl)sulfur diimide, and 2,4,6-tri-t-butyl-N-sulfinylaniline (7).The sulfur diimide was considered to be formed via intermediary 2,4,6-tri-t-butylthionitrosobenzene, which was trapped by oxygen to give the N-sulfinyl derivative 7.
Thermolysis of o-Alkylnitrosobenzenes. Unusually Ready Hydrogen Shift involving a Nitroso-group
Okazaki, Renji,Watanabe, Masako,Inagaki, Yoshio,Inamoto, Naoki
, p. 1365 - 1369 (2007/10/02)
Thermolysis of 2,4-di-t-butyl-6-methylnitrosobenzene (1) in benzene afforded the corresponding aniline (2) and 5,7-di-t-butyl-2,1-benzisoxazole (3) in the ratio of 1:2; in methanol 2-t-butyl-4-methoxy-6-methylaniline (4) and 1-hydroxyimino-2,4-di-t-butyl-