35532-73-1

Basic information

• Product Name: 2,4-DI(TERT-BUTYL)-6-METHYLANILINE
• Synonyms: 2,4-DI(TERT-BUTYL)-6-METHYLANILINE
• CAS NO: 35532-73-1
• Molecular Formula: C₁₅H₂₅N
• Molecular Weight: 219.37
• Mol File: 35532-73-1.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2,4-DI(TERT-BUTYL)-6-METHYLANILINE(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-DI(TERT-BUTYL)-6-METHYLANILINE(35532-73-1)
• EPA Substance Registry System: 2,4-DI(TERT-BUTYL)-6-METHYLANILINE(35532-73-1)

Safety Data

• Hazardous Substances Data: 35532-73-1(Hazardous Substances Data)

Upstream product

• 20444-30-8 1,5-di-tert-butyl-3-methyl-2-nitrobenzene 
• 58712-16-6 (E)-6-hydroxyimino-1,3,5-tri-t-butyl-5-methyl-1,3-cyclohexadiene 
• 67-56-1 methanol 
• 25798-68-9 2,4-di-t-butyl-6-methylnitrosobenzene 
• 58949-88-5 2,4-di-t-butyl-6-methyl-N-(thiosulfinyl)aniline 
• 4074-25-3 2,4,6-tri-tert-butylnitrobenzene 
• 108-88-3 toluene 
• 15181-11-0 3, 5-di-tert-butyltoluene 
• 109072-78-8 C₂₄H₃₈N₂OS₂ 

Downstream Products

• 69594-90-7 1,5-Di-tert-butyl-2-isothiocyanato-3-methyl-benzene 
• 68065-79-2 N-(2-Methyl-4,6-di-tert.-butylphenyl)-N'-neopentylthioharnstoff 
• 78923-66-7 N-Trimethylsilyl-6-methyl-2,4-di-t-butylaniline 
• 98039-74-8 1,3-Bis-(2,4-di-tert-butyl-6-methyl-phenyl)-2,4-bis-(2,4,6-tri-tert-butyl-phenyl)-[1,3,2,4]diazadiphosphetidine 
• 538315-30-9 methyl 7-[[2,4-bis(1,1-dimethylethyl)-6-methylphenyl]-aminocarbonyl]-3-methyl-2,4,6-octatrienoate 
• 68065-78-1 N-(2-Methyl-4,6-di-tert.-butylphenyl)-N'-isobutylthioharnstoff 
• 69034-88-4 N-sulfinyl-2,4-di-t-butyl-6-methylaniline 
• 80525-28-6 2,9-Bis-(2,4-di-tert-butyl-6-methyl-phenyl)-anthra[2,1,9-def;6,5,10-d'e'f']diisoquinoline-1,3,8,10-tetraone 
• 114159-50-1 2,4-di-tert-butyl-6,N-dimethyl-aniline 
• 4282-22-8 2,4-di-tert-butyl-6,N,N-trimethyl-aniline 
• 101261-01-2 4,6-di-tert-butyl-2-methyl-3-nitro-aniline 

Relevant articles and documents

THERMOLYSIS OF 6-HYDROXYIMINO-1,3,5-TRI-t-BUTYL-5-METHYL-1,3-CYCLOHEXADIENE

Mechanism of the thermolysis of the title compound has been proposed, which begins with a homolytic cleavage leading to t-butyl radical and 2,4-di-t-butyl-6-methyl-1-nitrosobenzene.The reaction of the nitrosobenzene with t-butyl radical generated from photolysis of 2,2'-dimethyl-2,2'-azopropane is also described.

1,3-CYCLOADDITIONS OF A THIONITROSO S-SULFIDE

The thionitroso S-sulfide 5 adds to (E)-cyclooctene, (E,Z)-1,5-cyclooctadiene, and norbornene to give 1,2,3-dithiazolidines, whereas enamines undergo electrophilic substitution.

Chemistry of N-Thiosulfinylanilines. V. Reactions of N-Thiosulfinylanilines with Nucleophilic Reagents

2,4-Di-t-butyl-6-methyl-N-(thiosulfinyl)aniline (1) gave 2,4-di-t-butyl-6-methylaniline in the reactions with such reagents as alkylamines, thiourea, butyllithium, alkylmagnesium halides, 1-(1-pyrrolidinyl)cyclopentene, and hydrogen sulfide.Triphenylphosphine reacted with 1 to give (2,4-di-t-butyl-6-methylphenylimino)triphenylphosphorane and bis(2,4-di-t-butyl-6-methylphenyl)sulfur diimide.Reaction of triphenylphosphine with 2,4,6-tri-t-butyl-7,8-dithia-9-azabicyclonona-2,4,9-triene afforded 2,4,6-tri-t-butylaniline, bis(2,4,6-tri-t-butylphenyl)sulfur diimide, and 2,4,6-tri-t-butyl-N-sulfinylaniline (7).The sulfur diimide was considered to be formed via intermediary 2,4,6-tri-t-butylthionitrosobenzene, which was trapped by oxygen to give the N-sulfinyl derivative 7.