35702-75-1

Basic information

• Product Name: 1,6-Octadiene, 8-methoxy-, (E)-
• CAS NO: 35702-75-1
• Molecular Formula: C9H16O
• Molecular Weight: 140.225
• Mol File: 35702-75-1.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1,6-Octadiene, 8-methoxy-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,6-Octadiene, 8-methoxy-, (E)-(35702-75-1)
• EPA Substance Registry System: 1,6-Octadiene, 8-methoxy-, (E)-(35702-75-1)

Safety Data

• Hazardous Substances Data: 35702-75-1(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 106-99-0 buta-1,3-diene 
• 201230-82-2 carbon monoxide 
• 108-91-8 cyclohexylamine 

Downstream Products

• 139388-97-9 α-(2E,7-octadienyl)-β-ethylhydrocinnamaldehyde methyline 
• 127980-68-1 N-(2E,7-octadienyl)-N-methyl-α-phenyl(n-propyl)amine 
• 127980-69-2 N-(2E,7-octadienyl)-N-methyl-α-phenyl(n-butyl)amine 
• 127980-70-5 N-(2E,7-octadienyl)-N-methyl-α-phenyl(n-pentyl)amine 
• 592-42-7 1,5-Hexadien 
• 1076-66-0 3-phenyl-1,5-hexadiene 
• 58463-02-8 (1E,5E)-1,6-diphenyl-1,5-hexadiene 
• 56644-04-3 (E)-1-phenyl-1,5-hexadiene 
• 74120-63-1 (E)-1,4-diphenyl-1,5-hexadiene 
• 87414-95-7 O-(N-2E,7-Octadienylamino)anisole 
• 119803-86-0 phenyl 2E,7-octadienyl sulfide 
• 130914-62-4 1-(2E,7-Octadienyl)-α-tolyl sulfide 
• 929-56-6 1-methoxyoctane 
• 139388-72-0 α-(2E,7-octadienyl)-β-(n-hexyl)hydrocinnamaldehyde 

Relevant articles and documents

Efficient catalysts for telomerization of butadiene with amines

In situ-generated N-heterocyclic carbene (NHC) palladium catalysts and isolated NHC-palladium complexes have been tested for the telomerization reaction of 1,3-butadiene with primary and secondary amines. Superior catalyst activity (TON up to 400.000) and

Palladium-Catalyzed Methoxycarbonylation of 1,3-Butadiene: Catalysis and Mechanistic Studies

The palladium-catalyzed methoxycarbonylation of 1,3-butadiene to methyl 3-pentenoate has been studied. Intermediates of the proposed catalytic cycle were synthesized and the elementary steps of the reaction have been investigated in detail. It is shown th

Palladium-catalyzed reactions for the synthesis of fine chemicals, 14([≠]) control of chemo- and regioselectivity in the palladium-catalyzed telomerization of butadiene with methanol - Catalysis and mechanism

The palladium-catalyzed telomerization reaction of butadiene with methanol has been examined with the aim of controlling the chemoselectivity (telomerization vs. dimerization products) and regioselectivity (linear vs. branched telomerization product) of the reaction. We have shown that the reaction temperature, ligand-to-metal ratio and ratio of substrates exert a large influence on the selectivity of the reaction. Selectivities of up to 97% for the desired linear telomerization product 1 can be achieved below 50 °C by employing both low PPh3/Pd and butadiene/methanol ratios. Mono(phosphane)palladium(0)-diallyl ether complexes, Ar3P- Pd[(CH2=CHCH2)2O] (5), serve as new catalysts for the reaction. In order to gain a mechanistic understanding of the observed selectivity effects, we synthesized the phosphane(octadienyl)palladium(II) complexes 7a and 9a as model compounds for key reaction intermediates and examined their stoichiometric reactions with the methoxide nucleophile. Based on our results, we propose an extension of the known telomerization mechanism that accounts for the observed selectivity effects.