357425-93-5

Basic information

• Product Name: 1,5-methano-2,3,4,5-tetrahydro-1H-3-benzazepine p-toluenesulfonic acid salt
• Synonyms: 1,5-methano-2,3,4,5-tetrahydro-1H-3-benzazepine p-toluenesulfonic acid salt
• CAS NO: 357425-93-5
• Molecular Weight: 331.436
• Mol File: 357425-93-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1,5-methano-2,3,4,5-tetrahydro-1H-3-benzazepine p-toluenesulfonic acid salt(CAS DataBase Reference)
• NIST Chemistry Reference: 1,5-methano-2,3,4,5-tetrahydro-1H-3-benzazepine p-toluenesulfonic acid salt(357425-93-5)
• EPA Substance Registry System: 1,5-methano-2,3,4,5-tetrahydro-1H-3-benzazepine p-toluenesulfonic acid salt(357425-93-5)

Safety Data

• Hazardous Substances Data: 357425-93-5(Hazardous Substances Data)

Upstream product

• 29427-69-8 3-oxoindan-1-carboxylic acid 
• 474024-38-9 3-[1,3]dioxolan-2-ylidene-3H-indene-1-carbonitrile 
• 19472-74-3 2-(2-bromophenyl)acetonitrile 
• 2856-63-5 2-Chlorophenylacetonitrile 
• 583-53-9 2,3-dibromobenzene 
• 542-92-7 cyclopenta-1,3-diene 
• 26326-70-5 (1R,2R,3S,4S)-1,2,3,4-tetrahydro-1,4-methanonaphthalene-2,3-diol 
• 29427-70-1 methyl 3-oxo-2,3-dihydro-1H-indene-1-carboxylate 
• 357426-11-0 methyl 3-cyano-3-(trimethylsilanyloxy)indan-1-carboxylate 
• 104-15-4 toluene-4-sulfonic acid 
• 230615-48-2 3-benzyl-2,3,4,5-tetrahydro-1,5-methano-1H-3-benzazepine 
• 357426-13-2 1,5-methano-2-oxo-2,3,4,5-tetrahydro-1H-3-benzazepine 

Downstream Products

• 230615-51-7 1-(10-aza-tricyclo[6.3.1.0^2,7]dodeca-2⁽⁷⁾,3,5-trien-10-yl)-2,2,2-trifluoro-ethanone 

Relevant articles and documents

Preparation of 1,5-methano-2,3,4,5-tetrahydro-1H-3-benzazepine via Pd-catalyzed cyclization

(Equation Presented) A new approach to prepare 1,5-methano-2,3,4,5- tetrahydro-1H-3-benzanepine (1) is discussed. This strategy utilized a tandem Michael addition and Pd-catalyzed cyclization to afford cyanobenzofulvene acetal 13. This indene intermediate

A general route to the synthesis of 1,5-methano- and 1,5-ethano-2, 3,4,5-tetrahydro-1h-3-benzazepines

A general approach to preparing 1,5-methano-(1) and l,5-ethano-2,3,4,5- tetrahydro-lff-3-benzazepine (2) is discussed. This strategy involves converting an indanone or tetralone (4) to a cyanohydrin (3) which is subjected to hydrogenolysis followed by lac

Process for the preparation of 1,3-substituted indenes and aryl-fused azapolycyclic componunds

The present invention relates to processes for the preparation of any of the intermediate 1,3-substituted indenes of the formulae (Ia), (Ib) and (Ic) or a mixture thereof: wherein R1, R2, R3, R4, and R5 are defined herein. Compounds of formulae (Ia), (Ib) and (IC) or mixtures thereof are useful in the preparation of compounds of formula (II): wherein R2, R3 and R6 are also defined herein.