358-81-6Relevant academic research and scientific papers
Catalytic enantioselective aldol reaction to ketones
Oisaki, Kounosuke,Zhao, Dongbo,Kanai, Motomu,Shibasaki, Masakatsu
, p. 7164 - 7165 (2007/10/03)
An enantioselective aldol reaction between ketones and ketene silyl acetals is described using CuF-chiral phosphine as a catalyst. The key for high enantioselectivity was the development of a novel ligand derived from Taniaphos combined with the unique ac
Cleavage of the C-Si bond in trifluoro(phenyl)silane with aliphatic alcohols
Voronkov,Boyarkina,Gebel',Albanov,Basenko
, p. 1927 - 1929 (2008/02/03)
Trifluoro(phenyl)silane reacts with aliphatic alcohols under reflux. The reaction involves not only Si-F bond cleavage to form ethoxyfluoro(phenyl) silanes, but also C-Si bond cleavage to form benzene and alkoxyfluoro- and tetraalkoxysilanes. The formation of the latter products was proved by 19F and 29Si NMR spectroscopy and also by model disproportionation reactions of trifluoro(phenyl)silane with trimethoxy-(phenyl)-, tetramethoxy-, or tetraethoxysilanes.
