3582-85-2Relevant academic research and scientific papers
Copper-catalyzed hydrophosphinations of styrenes in water at room temperature
Isley, Nicholas A.,Linstadt, Roscoe T. H.,Slack, Eric D.,Lipshutz, Bruce H.
, p. 13196 - 13200 (2014)
Copper-catalyzed hydrophosphinations of styrenyl systems in water, at room temperature is herein reported, enabled by our 'designer' surfactant TPGS-750-M. This is an attractive alternative to the more common Pd and Pt catalyzed versions.
Phosphinoyl Radical Initiated Vicinal Cyanophosphinoylation of Alkenes
Zhang, Pei-Zhi,Zhang, Ling,Li, Jian-An,Shoberu, Adedamola,Zou, Jian-Ping,Zhang, Wei
supporting information, p. 5537 - 5540 (2017/10/25)
A double-functionalization reaction of alkenes through Mn(OAc)3-mediated phosphinoyl radical addition followed by CuCN-catalyzed cyanation is introduced. This one-pot reaction is performed under mild conditions to afford vicinal cyanophosphinoylation products.
Direct radical acetoxyphosphorylation of styrenes mediated by manganese(III)
Zhou, Shao-Fang,Li, Da-Peng,Liu, Kui,Zou, Jian-Ping,Asekun, Olayinka Taiwo
, p. 1214 - 1220 (2015/01/30)
Direct radical acetoxyphosphorylation of styrenes mediated by Mn(OAc)3 with diphenylphosphine oxide and dialkyl phosphites was described, and a new type of difunctionalization of alkenes was achieved.
