35972-85-1Relevant academic research and scientific papers
Reduction of Thionoesters to Ethers by Triorganotin Hydrides
Smith, Colin,Tunstad, Linda M.,Gutierrez, Carlos G.
, p. 257 - 260 (2007/10/02)
Esters 1 are efficiently deoxygenated to the corresponding ethers 3 in two steps by first conversion to the thionoesters 2 and subsequent reduction of these by triorganotin hydrides.
Carbophilic versus thiophilic attack in the reaction of metallated aromates and heteroaromates with carbon disulfide
Verkruijsse, H. D.,Brandsma, L.
, p. 95 - 98 (2007/10/02)
Copper(I) halides catalyse the formation of carbodithioates RCSSLi in the reaction of aryl- or heteroaryl-lithium reagents with carbon disulfide.Subsequent addition of methyl iodide gives the dithioesters RCSSCH3 in highh yields.Appreciable amounts of the methyl sulfides RSCH3 and tars are obtained when the reaction with CS2 is carried out in the absence of copper(I) salts, especially in the case of more basic organoalkali compounds.
