360-11-2Relevant articles and documents
Alkali Metal Fluorides in Fluorinated Alcohols: Fundamental Properties and Applications to Electrochemical Fluorination
Shida, Naoki,Takenaka, Hiroaki,Gotou, Akihiro,Isogai, Tomohiro,Yamauchi, Akiyoshi,Kishikawa, Yosuke,Nagata, Yuuya,Tomita, Ikuyoshi,Fuchigami, Toshio,Inagi, Shinsuke
, p. 16128 - 16133 (2021/07/26)
Fundamental properties of alkali metal fluorides (MF, M = Cs, K) dissolved in 1,1,1,3,3,3-hexafluoroisopropanol (HFIP) or in 3,3,3-trifluoroethanol (TFE) are investigated, including solubility, conductivity, and viscosity. Solid-state structures of single crystals obtained from CsF/HFIP and CsF/TFE are described for the first time, giving insights into the multiple interactions between fluorinated alcohols and CsF. Applications in electrochemical fluorination reactions are successfully demonstrated.
Pd-Catalyzed Transfer of Difluorocarbene for Three Component Cross-Coupling?
Xu, Zhi-Wei,Zhang, Wei,Lin, Jin-Hong,Jin, Chuan-Ming,Xiao, Ji-Chang
supporting information, p. 1647 - 1650 (2020/10/19)
Outstanding accomplishments have been achieved in the chemistry of difluorocarbene, but transition- metal-catalyzed transfer of difluorocarbene for coupling remains a challenging task. Herein, we describe a Pd-catalyzed coupling of difluorocarbene with two aryl carbon centers to give difluoromethylenation products, which cannot be obtained by any previous difluorocarbene-transformation method.
DIFLUOROMETHYL AND DIFLUOROMETHYLENE TRANSFER REAGENTS
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Paragraph 0022; 0096, (2020/01/22)
Disclosed herein are borazine, borate, and azaborinine compounds and compositions, methods of making said compounds and compositions, and methods of forming aromatic difluorocarbon compounds and difluorocarbon compounds.
