361-98-8Relevant academic research and scientific papers
A nickel-catalyzed: Anti -carbometallative cyclization of alkyne-azides with organoboronic acids: Synthesis of 2,3-diarylquinolines
Ranjith Kumar, Gadi,Kumar, Ravi,Rajesh, Manda,Sridhar Reddy, Maddi
, p. 759 - 762 (2018/02/06)
An anti-carbonickelative cyclization via reversible alkenylnickel E/Z isomerization of 2-azido phenyl propargyl alcohols with aryl boronic acids is achieved using Ni(acac)2 as the catalyst to access 2,3-diaryl quinolines. It represents a rare example of trapping the vinyl metal intermediate with a nitrogen center, a non-carbon center electrophile.
